Effect of MoZrN Coating on a Steel XC100
The zirconium nitride ZrN coatings are deposited on substrates of XC100 steel using physical vapour deposition (PVD) technique. Coatings based on nitrides of transition metals (Nb, Zr, Ti, V, ...) developed by PVD are known to increase the life of cutting tools, and so they naturally have seen a rap...
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Інститут металофізики ім. Г.В. Курдюмова НАН України
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| Zitieren: | Effect of MoZrN Coating on a Steel XC100 / A. Abboudi, B. Meddour, B. Chermime, H. Djebaili, and M. Brioua // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 7. — С. 903-909. — Бібліогр.: 9 назв. — англ. |
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irk-123456789-1125962017-01-24T03:02:28Z Effect of MoZrN Coating on a Steel XC100 Abboudi, A. Meddour, B. Chermime, B. Djebaili, H. Brioua, M. Металлические поверхности и плёнки The zirconium nitride ZrN coatings are deposited on substrates of XC100 steel using physical vapour deposition (PVD) technique. Coatings based on nitrides of transition metals (Nb, Zr, Ti, V, ...) developed by PVD are known to increase the life of cutting tools, and so they naturally have seen a rapid industrial growth. It is possible to produce ZrN-coatings with variations of nitrogen partial pressure, the residual stresses, the thickness of the thin film, and the friction coefficient depending on the nitrogen content. Usage of nitrogen is a good way to enhance wear resistance and effectiveness in tribological applications. Покриття з нітриду цирконію ZrN наносилися на підложжя зі сталі XC100 з використанням технології вакуумного напорошення (PVD). Покриття на основі нітридів перехідних металів (Nb, Zr, Ti, V, ...), створені з використанням PVD-методи, як відомо, збільшують термін придатности різального інструменту; тому спостерігається швидкий ріст їх промислового виробництва. Наявна можливість виготовлення ZrN-покриттів зі змінними парціальним тиском азоту, залишковими напруженнями, товщиною тонкої плівки та коефіцієнтом тертя залежно від вмісту азоту. Використання азоту є перспективним шляхом підвищення зносостійкости та ефективности в трибології. Покрытия из нитрида циркония ZrN наносились на подложки из стали XC100 с использованием метода вакуумного напыления (PVD). Покрытия на основе нитридов переходных металлов (Nb, Zr, Ti, V, ...), созданные с использованием PVD-технологии, как известно, увеличивают срок службы режущего инструмента; поэтому наблюдается быстрый рост их промышленного производства. Имеется возможность изготавливать ZrN-покрытия с изменяемыми парциальным давлением азота, остаточными напряжениями, толщиной тонкой плёнки и коэффициентом трения в зависимости от содержания азота. Использование азота является перспективным путём повышения износостойкости и эффективности в трибологии. 2016 Article Effect of MoZrN Coating on a Steel XC100 / A. Abboudi, B. Meddour, B. Chermime, H. Djebaili, and M. Brioua // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 7. — С. 903-909. — Бібліогр.: 9 назв. — англ. 1024-1809 DOI: 10.15407/mfint.38.07.0903 PACS: 62.20.Qp, 68.55.jd, 81.15.Cd, 81.15.Dj, 81.15.Kk, 81.40.Pq, 81.65.Lp http://dspace.nbuv.gov.ua/handle/123456789/112596 en Металлофизика и новейшие технологии Інститут металофізики ім. Г.В. Курдюмова НАН України |
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Металлические поверхности и плёнки Металлические поверхности и плёнки |
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Металлические поверхности и плёнки Металлические поверхности и плёнки Abboudi, A. Meddour, B. Chermime, B. Djebaili, H. Brioua, M. Effect of MoZrN Coating on a Steel XC100 Металлофизика и новейшие технологии |
| description |
The zirconium nitride ZrN coatings are deposited on substrates of XC100 steel using physical vapour deposition (PVD) technique. Coatings based on nitrides of transition metals (Nb, Zr, Ti, V, ...) developed by PVD are known to increase the life of cutting tools, and so they naturally have seen a rapid industrial growth. It is possible to produce ZrN-coatings with variations of nitrogen partial pressure, the residual stresses, the thickness of the thin film, and the friction coefficient depending on the nitrogen content. Usage of nitrogen is a good way to enhance wear resistance and effectiveness in tribological applications. |
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Article |
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Abboudi, A. Meddour, B. Chermime, B. Djebaili, H. Brioua, M. |
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Abboudi, A. Meddour, B. Chermime, B. Djebaili, H. Brioua, M. |
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Abboudi, A. |
| title |
Effect of MoZrN Coating on a Steel XC100 |
| title_short |
Effect of MoZrN Coating on a Steel XC100 |
| title_full |
Effect of MoZrN Coating on a Steel XC100 |
| title_fullStr |
Effect of MoZrN Coating on a Steel XC100 |
| title_full_unstemmed |
Effect of MoZrN Coating on a Steel XC100 |
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effect of mozrn coating on a steel xc100 |
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Інститут металофізики ім. Г.В. Курдюмова НАН України |
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2016 |
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Металлические поверхности и плёнки |
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http://dspace.nbuv.gov.ua/handle/123456789/112596 |
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Effect of MoZrN Coating on a Steel XC100 / A. Abboudi, B. Meddour, B. Chermime, H. Djebaili, and M. Brioua // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 7. — С. 903-909. — Бібліогр.: 9 назв. — англ. |
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903
PACS numbers:62.20.Qp, 68.55.jd,81.15.Cd,81.15.Dj,81.15.Kk,81.40.Pq, 81.65.Lp
Effect of MoZrN Coating on a Steel XC100
A. Abboudi, B. Meddour*, B. Chermime, H. Djebaili*, and M. Brioua
Université Colonel Hadj Lakhdar,
Batna, Algeria
*LASPI2A, Université Abbas Laghrour de Khenchela,
BP 1252 Route de Batna Khenchela,
40004 Khenchela, Algeria
The zirconium nitride ZrN coatings are deposited on substrates of XC100
steel using physical vapour deposition (PVD) technique. Coatings based on
nitrides of transition metals (Nb, Zr, Ti, V, ) developed by PVD are known
to increase the life of cutting tools, and so they naturally have seen a rapid
industrial growth. It is possible to produce ZrN-coatings with variations of
nitrogen partial pressure, the residual stresses, the thickness of the thin
film, and the friction coefficient depending on the nitrogen content. Usage of
nitrogen is a good way to enhance wear resistance and effectiveness in tribo-
logical applications.
Key words: zirconium nitride, coating, substrate, PVD-technique, tribologi-
cal applications.
Покриття з нітриду цирконію ZrN наносилися на підложжя зі сталі
XC100 з використанням технології вакуумного напорошення (PVD). Пок-
риття на основі нітридів перехідних металів (Nb, Zr, Ti, V, ), створені з
використанням PVD-методи, як відомо, збільшують термін придатности
різального інструменту; тому спостерігається швидкий ріст їх промисло-
вого виробництва. Наявна можливість виготовлення ZrN-покриттів зі
змінними парціальним тиском азоту, залишковими напруженнями, тов-
щиною тонкої плівки та коефіцієнтом тертя залежно від вмісту азоту. Ви-
користання азоту є перспективним шляхом підвищення зносостійкости
та ефективности в трибології.
Corresponding author: Abedelaziz Abboudi
E-mail: aboudiabdelaziz23@gmail.com
Please cite this article as: A. Abboudi, B. Meddour, B. Chermime, H. Djebaili, and
M. Brioua, Effect of MoZrN Coating on a Steel XC100, Metallofiz. Noveishie Tekhnol.,
38, No. 7: 903—909 (2016), DOI: 10.15407/mfint.38.07.0903.
Металлофиз. новейшие технол. / Metallofiz. Noveishie Tekhnol.
2016, т. 38, № 7, сс. 903—909 / DOI: 10.15407/mfint.38.07.0903
Оттиски доступны непосредственно от издателя
Фотокопирование разрешено только
в соответствии с лицензией
2016 ИМФ (Институт металлофизики
им. Г. В. Курдюмова НАН Украины)
Напечатано в Украине.
904 A. ABBOUDI, B. MEDDOUR, B. CHERMIME et al.
Ключові слова: нітрид цирконію, покриття, підкладка, PVD-метод, три-
бологія.
Покрытия из нитрида циркония ZrN наносились на подложки из стали
XC100 с использованием метода вакуумного напыления (PVD). Покрытия
на основе нитридов переходных металлов (Nb, Zr, Ti, V, ), созданные с
использованием PVD-технологии, как известно, увеличивают срок служ-
бы режущего инструмента; поэтому наблюдается быстрый рост их про-
мышленного производства. Имеется возможность изготавливать ZrN-
покрытия с изменяемыми парциальным давлением азота, остаточными
напряжениями, толщиной тонкой плёнки и коэффициентом трения в за-
висимости от содержания азота. Использование азота является перспек-
тивным путём повышения износостойкости и эффективности в триболо-
гии.
Ключевые слова: нитрид циркония, покрытие, подложка, PVD-метод,
трибология.
(Received April 12, 2016)
1. INTRODUCTION
The use of coatings of the nitride of transition metals has been ex-
plored with success in the past decades, due to properties such as high
hardness, biocompatibility, wear and corrosion resistance and thermal
stability. Titanium nitride is the most studied. However, zirconium,
niobium nitrides, and vanadium, among others, also have similar pro-
tective properties [1]. Authors agree on the values of hardness of about
25 GPa for TiN [2, 3].
In order to determine the process of forming of these films, depend-
ing on the used equipment, a strict control of all deposition parameters
is required. Currently, the technique most commonly used is the coat-
ing of metal surfaces with reactive nitrides magnetron sputtering
which enables the handling of a large number of parameters such as
energy deposition (bias), deposition rate (plasma current), residual
stresses of the layer thickness and a neutral reagent gas (Rodriguez et
al., 1994) showed that CrN compared to TiCN, ZrN, TiN [4] has the
wear rate is the lowest.
2. MATERIAL AND METHODS
The ZrN and MoZrN deposits are made in ENSAM (Ecole Nationale Su-
périeure d’Arts et Métiers) of Cluny using System Dual magnetron
sputtering (Nordiko 3500) (Fig. 1). We have processed to remove air to
create a vacuum of 10
6
Torr. Thereafter, we have set the desired polar-
ization with Argon fixation and progressive increase of the nitrogen
EFFECT OF MoZrN COATING ON A STEEL XC100 905
pressure.
XC100 was used as substrate material and polished to a surface
roughness of 0.09 mm, after the polishing process, the sample was ul-
trasonically cleaned in hot alkaline cleaning bath for at least 5 min and
then quenched. The target, composed of materials to be sprayed, are
connected to a radio frequency (RF) generator (13.56 MHz) power of a
variable from 0 to 1250 W), with Mo and Zr target and nitrogen gas as
reagent, a substrate XC100. Sources of Zr and Mo were installed on
each side of the chamber wall; the distance between the substrate and
the targets was fixed around 8 cm. The variation in the percentage of
Zirconium (Zr) is made by changing the voltage on the target (Zr) by
setting the voltage of the Mo target, a second series of depositions were
carried out by setting the voltage of the Zr target and varying the volt-
age of the Mo target, the deposition time is 100 min. The chemical
composition of the steel XC100 is given in the following Table 1.
3. RESULTS AND DISCUSSION
3.1. Thickness of Films According to the Deposition Time
According to Fig. 2, we see that the deposited thickness is linearly in-
Fig. 1. Device for magnetron sputtering: 1–cryogen secondary pump, 2–
enceinte of deposit, 3–mass flowmeters, 4–Baratron capacitance manome-
ter, 5–DC power supply, 6–RF generator 13.5 MHz, 7–impedance adapter,
8–pumping control system and pressure, 9–rotation of the motor carrier
substrates, 10–control system of the target caches and substrates.
TABLE 1. Chemical composition of the steel XC100.
XC100 C Mn S, P Si Cr Ni Cu
Percentage 0.95 0.25 S 0.025 0.15 0.15 0.2 0.2
906 A. ABBOUDI, B. MEDDOUR, B. CHERMIME et al.
creasing with deposition time. The deposition rate is 6.475 nm/min.
Therefore, the deposited mass per surface area of the substrate is
also XC100 linear with the deposition time.
3.2. Residual Stresses as a Function of the Thickness
The decrease of the stress when the thickness increase is attributed to
relaxation of the layer in surface. It is noted that the stress of ZrN lay-
ers (Fig. 3) is not constant with the thickness. It reaches a maximum
and then decreases to 100 nm to 250 nm. Such results have been re-
ported for layers of aluminium nitride [5, 6]. The stress peak is due to a
change in structure during growth of the layer.
3.3. Coefficient of Friction as a Function of the Thickness
The friction coefficient of the XC100 steel with the diamond indenter
is between 0.2 and 0.6; so, it is very large compared to that of the car-
bide inserts.
Figure 4 represents the coefficient of friction of a film according to
ZrN thickness; the friction coefficient of mono- and multilayer films
on XC100 steel is higher than that of the carbide films. It is between
0.08 and 0.11 and remains very low. For coating, the ZrN and MoZrN
coefficient of friction was between 0.2 and 0.3. The application of most
of ZrN and produced a collection MoZrN reduction equipment [7].
Moreover, the layers formed by magnetron sputtering to have a high
friction coefficient. Layers of CrN deposited on high-speed steel by arc
Fig. 2. Thickness of films according to the deposition time.
EFFECT OF MoZrN COATING ON A STEEL XC100 907
evaporation and to reduce the coefficient of friction was also obtained
by S.-C. Lee, W.-Y. Ho, and D. F. Lai [8].
3.4. Deposition Rate as a Function of % Nitrogen
In the studied range of nitrogen, there is a significant variation in the
deposition rate as a function of nitrogen (Fig. 5). It is noted that the
deposition rate decreases as the nitrogen increases, the decrease of the
deposition rate as a function of nitrogen is due to the increase in the
Fig. 4. Coefficient of friction as a function of the thickness.
Fig. 3. Residual stresses as a function of the thickness.
908 A. ABBOUDI, B. MEDDOUR, B. CHERMIME et al.
bias voltage of the target when the power applied generator; inducing
higher energy bombarding the target species; is increased.
4. CONCLUSION
The present study reflects the influence of various hard coatings on
steel XC100.
It appears that the ZrN layer deposited by magnetron sputtering
gives better results than the nitriding treatment [9]. Multilayer coat-
ings (MoZrN) and ZrN in all tests resist corrosion. This may be due to a
better adhesion of the coating on the substrate and a lower coefficient
of friction, which also reduces the cutting forces and the process is
more stable with respect to vibration, the thickness of the layer is very
significant on the surface.
The authors want to thank especially Prof. Caprian (ENSAM, Clu-
ny—Lyon, France) for has advice and collaboration during this work.
REFERENCES
1. D. Sangiovanni, L. Hultman, and V. Chirita, Acta Materialia, 59: 2121 (2011).
2. J. Richter, Surf. Coat. Technol., 162: 119 (2003).
3. N. Maria, M. Larsson, and H. Sture, Wear, 232: 221 (1999).
4. K. Kutschej, B. Rashkova, J. Shen, D. Edwards, C. Mitterer, and G. Dehm,
Thin Solid Films, 516: 369 (2007).
5. W. Kutschej, 7
ème
Symposium International sur les Tendances et Applications
des Films Minces ‘TAFT-2000’ (Nancy, France, 2000).
6. A. Richardt and A. Durand, La Pratique du Vide et des Dépôts de Couches
Minces (Paris: Fine: 1995).
Fig. 5. Deposition rate as a function of (% nitrogen).
EFFECT OF MoZrN COATING ON A STEEL XC100 909
7. H. L. Coldwell, R. C Dewes, D. K. Aspinwall, N. M. Renevier, and D. G. Teer,
Surf. Coat. Technol., 177—178: 716 (2004).
8. S.-C. Lee, W.-Y. Ho, and D. F. Lai, Materials Chemistry and Physics, 43: 266
(1996).
9. P. Panjan, B. Navinšek, A. Cvelbar, A. Zalar, and I. Milošev, Thin Solid Films,
281: 298 (1996).
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/HRV (Za stvaranje Adobe PDF dokumenata najpogodnijih za visokokvalitetni ispis prije tiskanja koristite ove postavke. Stvoreni PDF dokumenti mogu se otvoriti Acrobat i Adobe Reader 5.0 i kasnijim verzijama.)
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/NLD (Gebruik deze instellingen om Adobe PDF-documenten te maken die zijn geoptimaliseerd voor prepress-afdrukken van hoge kwaliteit. De gemaakte PDF-documenten kunnen worden geopend met Acrobat en Adobe Reader 5.0 en hoger.)
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/ENU (Use these settings to create Adobe PDF documents best suited for high-quality prepress printing. Created PDF documents can be opened with Acrobat and Adobe Reader 5.0 and later.)
>>
/Namespace [
(Adobe)
(Common)
(1.0)
]
/OtherNamespaces [
<<
/AsReaderSpreads false
/CropImagesToFrames true
/ErrorControl /WarnAndContinue
/FlattenerIgnoreSpreadOverrides false
/IncludeGuidesGrids false
/IncludeNonPrinting false
/IncludeSlug false
/Namespace [
(Adobe)
(InDesign)
(4.0)
]
/OmitPlacedBitmaps false
/OmitPlacedEPS false
/OmitPlacedPDF false
/SimulateOverprint /Legacy
>>
<<
/AddBleedMarks false
/AddColorBars false
/AddCropMarks false
/AddPageInfo false
/AddRegMarks false
/ConvertColors /ConvertToCMYK
/DestinationProfileName ()
/DestinationProfileSelector /DocumentCMYK
/Downsample16BitImages true
/FlattenerPreset <<
/PresetSelector /MediumResolution
>>
/FormElements false
/GenerateStructure false
/IncludeBookmarks false
/IncludeHyperlinks false
/IncludeInteractive false
/IncludeLayers false
/IncludeProfiles false
/MultimediaHandling /UseObjectSettings
/Namespace [
(Adobe)
(CreativeSuite)
(2.0)
]
/PDFXOutputIntentProfileSelector /DocumentCMYK
/PreserveEditing true
/UntaggedCMYKHandling /LeaveUntagged
/UntaggedRGBHandling /UseDocumentProfile
/UseDocumentBleed false
>>
]
>> setdistillerparams
<<
/HWResolution [2400 2400]
/PageSize [612.000 792.000]
>> setpagedevice
|