Analytical solution of the associative mean spherical approximation for the ion-dipole model
A simple electrolyte in a polar solvent is modelled by a mixture of polar hard spheres and equal diameter charged hard spheres with the possibility of ionic dimerization. The analytical solution of the associative mean spherical approximation (AMSA) for this model is derived to its full extent. E...
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| Date: | 1998 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
| Published: |
Інститут фізики конденсованих систем НАН України
1998
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| Series: | Condensed Matter Physics |
| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/118929 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Analytical solution of the associative mean spherical approximation for the ion-dipole model / M.F. Holovko, V. Kapko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 239-255. — Бібліогр.: 44 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | A simple electrolyte in a polar solvent is modelled by a mixture of polar hard
spheres and equal diameter charged hard spheres with the possibility of
ionic dimerization. The analytical solution of the associative mean spherical
approximation (AMSA) for this model is derived to its full extent. Explicit
expressions for pair correlation functions and dielectric constant in terms
of the AMSA are established. Some numerical calculations illustrate the
role of ionic association. |
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