Coexistence of paraelectric/proton-glass and ferroelectric (antiferroelectric) orders in Rb₁₋x(NH₄)xH₂AsO₄ crystals

This paper reviews the results of dielectric studies of the proton glass state in a mixed crystal Rubidium Ammonium Dihydrogen Arsenate (RADA) The coexistence of paraelectric/proton glass and ferroelectric or antiferroelectric orders, confirmed by other studies, has been discussed in detail. The...

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Збережено в:
Бібліографічні деталі
Дата:1998
Автори: Trybuła, Z., Stankowski, J.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 1998
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/118952
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Coexistence of paraelectric/proton-glass and ferroelectric (antiferroelectric) orders in Rb₁₋x(NH₄)xH₂AsO₄ crystals / Z. Trybuła, J. Stankowski // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 311-330. — Бібліогр.: 52 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:This paper reviews the results of dielectric studies of the proton glass state in a mixed crystal Rubidium Ammonium Dihydrogen Arsenate (RADA) The coexistence of paraelectric/proton glass and ferroelectric or antiferroelectric orders, confirmed by other studies, has been discussed in detail. The phase diagram of RADA is asymmetric. The proton glass state exists for ammonium concentration in the range of 0.1 < x < 0.5 . The phase diagram of deuterated DRADA is presented. The proton glass state region in DRADA, 0.2 < x < 0.35 is narrower than that for non-deuterated RADA. The effects of hydrostatic pressure on the dielectric properties in the proton glass state are presented. The glass temperature Tg decreases with pressure and is expected to vanish at 5 kbar. Low temperature behaviour is still an open question, since there is no experimental evidence of Tg(p) dependence below 4K for proton glass systems.