Effects of anharmonicity of current-phase relation in Josephson junctions

The aim of this review is the analysis of dynamical properties of Josephson junctions (JJ) with anharmonic current-phase relation (CPR). Firstly, discussion of theoretical foundation of anharmonic CPR in different Josephson structures and their experimental observation are presented. The influence o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Datum:2015
1. Verfasser: Askerzade, I.N.
Format: Artikel
Sprache:English
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2015
Schriftenreihe:Физика низких температур
Online Zugang:http://dspace.nbuv.gov.ua/handle/123456789/122056
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Effects of anharmonicity of current-phase relation in Josephson junctions (Review Article) / I.N. Askerzade // Физика низких температур. — 2015. — Т. 41, № 4. — С. 315-337. — Бібліогр.: 91 назв. — англ.

Institution

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-122056
record_format dspace
spelling irk-123456789-1220562017-06-27T03:03:02Z Effects of anharmonicity of current-phase relation in Josephson junctions Askerzade, I.N. The aim of this review is the analysis of dynamical properties of Josephson junctions (JJ) with anharmonic current-phase relation (CPR). Firstly, discussion of theoretical foundation of anharmonic CPR in different Josephson structures and their experimental observation are presented. The influence of anisotropy and multiband effects on CPR of JJ are analyzed. We present recent theoretical study results of the anharmonic CPR influence on I–V curve, plasma frequency, and dynamics of long JJ. Results of study of Shapiro steps in I–V curve of anharmonic JJ are also presented. Finally, CPR anharmonicity effect on characteristics of JJ-based qubits is discussed. 2015 Article Effects of anharmonicity of current-phase relation in Josephson junctions (Review Article) / I.N. Askerzade // Физика низких температур. — 2015. — Т. 41, № 4. — С. 315-337. — Бібліогр.: 91 назв. — англ. 0132-6414 PACS: 74.50.+r, 03.67.-a, 85.25.Cp http://dspace.nbuv.gov.ua/handle/123456789/122056 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description The aim of this review is the analysis of dynamical properties of Josephson junctions (JJ) with anharmonic current-phase relation (CPR). Firstly, discussion of theoretical foundation of anharmonic CPR in different Josephson structures and their experimental observation are presented. The influence of anisotropy and multiband effects on CPR of JJ are analyzed. We present recent theoretical study results of the anharmonic CPR influence on I–V curve, plasma frequency, and dynamics of long JJ. Results of study of Shapiro steps in I–V curve of anharmonic JJ are also presented. Finally, CPR anharmonicity effect on characteristics of JJ-based qubits is discussed.
format Article
author Askerzade, I.N.
spellingShingle Askerzade, I.N.
Effects of anharmonicity of current-phase relation in Josephson junctions
Физика низких температур
author_facet Askerzade, I.N.
author_sort Askerzade, I.N.
title Effects of anharmonicity of current-phase relation in Josephson junctions
title_short Effects of anharmonicity of current-phase relation in Josephson junctions
title_full Effects of anharmonicity of current-phase relation in Josephson junctions
title_fullStr Effects of anharmonicity of current-phase relation in Josephson junctions
title_full_unstemmed Effects of anharmonicity of current-phase relation in Josephson junctions
title_sort effects of anharmonicity of current-phase relation in josephson junctions
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2015
url http://dspace.nbuv.gov.ua/handle/123456789/122056
citation_txt Effects of anharmonicity of current-phase relation in Josephson junctions (Review Article) / I.N. Askerzade // Физика низких температур. — 2015. — Т. 41, № 4. — С. 315-337. — Бібліогр.: 91 назв. — англ.
series Физика низких температур
work_keys_str_mv AT askerzadein effectsofanharmonicityofcurrentphaserelationinjosephsonjunctions
first_indexed 2025-07-08T21:03:42Z
last_indexed 2025-07-08T21:03:42Z
_version_ 1837114194333270016
fulltext © I.N. Askerzade, 2015 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4, pp. 315–337 Effects of anharmonicity of current-phase relation in Josephson junctions (Review Article) I.N. Askerzade Computer Engineering Department and Center of Excellence of Superconductivity Research of Turkey, Ankara University, Ankara 06100, Turkey Institute of Physics of Azerbaijan National Academy of Sciences, Baku Az-1143, Azerbaijan E-mail: Iman.Askerzade@science.ankara.edu.tr Received September 18, 2014, published online February 23, 2015 The aim of this review is the analysis of dynamical properties of Josephson junctions (JJ) with anharmonic current-phase relation (CPR). Firstly, discussion of theoretical foundation of anharmonic CPR in different Jo- sephson structures and their experimental observation are presented. The influence of anisotropy and multiband effects on CPR of JJ are analyzed. We present recent theoretical study results of the anharmonic CPR influence on I–V curve, plasma frequency, and dynamics of long JJ. Results of study of Shapiro steps in I–V curve of an- harmonic JJ are also presented. Finally, CPR anharmonicity effect on characteristics of JJ-based qubits is dis- cussed. PACS: 74.50.+r Tunneling phenomena; Josephson effects; 03.67.-a Quantum information; 85.25.Cp Josephson devices; Keywords: Josephson junction, two-band superconductors, qubits, current-phase relation, anharmonicity. Contents 1. Introduction .......................................................................................................................................... 315 2. Influence of anisotropy and multiband effects of superconducting state on the CPR of JJ .................. 316 2.1. JJ based on d-wave superconductors ............................................................................................ 316 2.2. JJ between two-band superconductors ......................................................................................... 318 2.3. CPR relation for JJ structures with FM and AFM layers .............................................................. 319 2.4. Experimental results of CPR investigations in different Josephson structures ............................. 320 3. Influence of anharmonic effects of CPR on JJ dynamics .................................................................... 321 3.1. Anharmonic effects in I–V curve .................................................................................................. 321 3.2. Plasma frequency of JJ with anharmonic CPR ............................................................................. 325 3.3. Shapiro steps in I–V curve of JJ with anharmonic CPR ............................................................... 326 3.4. Inluence of anharmonic CPR on long JJ dynamics ...................................................................... 328 4. Qubits based on JJ with anharmonic CPR ............................................................................................ 329 4.1. Qubits ........................................................................................................................................... 329 4.2. Influence of anharmonic CPR on qubit characteristics ................................................................. 331 5. Conclusions .......................................................................................................................................... 334 References ................................................................................................................................................ 335 1. Introduction The Josephson effect was discovered by Brian Josephson [1]. The stationary Josephson effect was first observed exper- imentally by Rowell [2], and the nonstationary Josephson effect was observed by Yanson et al. [3]. Since that time, there has been a continuously growing interest in the funda- mental physics and applications of this effect. The achieve- ments in Josephson-junction (JJ) technology have made it possible to develop a variety of sensors for detecting ultralow magnetic fields and weak electromagnetic radiation; they have also enabled the fabrication, testing, and application of ultrafast digital rapid single flux quantum (RSFQ) circuits as well as the design of large-scale integrated circuits for signal processing and general purpose computing [4,5]. I.N. Askerzade 316 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 It is clear that the Josephson effect, the 50th anniver- sary of which was celebrated in 2012, remains one of the most spectacular manifestations of quantum mechanics in all of experimental science. At its most fundamental level the Josephson effect is nothing more than the electronic analogue of interference phenomena in optical physics. But from this humble premise springs a huge range of physical phenomena and electronics applications which placed Josephson devices at the heart of physics research during the second half of the century of superconductivity and beyond. The Josephson effect may be observed in a variety of structures. To realize such structures it is enough to fabri- cate a “weak” place interrupting the supercurrent flow in a superconductor or suppress the ability of a superconductor to carry a current, e.g., by deposition of a normal metal on its top, by implantation of impurities within a restricted volume, or by changing the sample geometry. One main characteristic of a JJ is the current-phase relation (CPR). Only in few cases CPR reduces to classical sinusoidal form with critical current cI [6,7]: ( ) = sin .S cI I (1) Modern aspects of the supercurrent SI dependence on the phase difference and the forms this dependence takes in Josephson junctions of different types ( superconductor– normal–superconductor, superconductor–insulator–super- conductor, double barrier, superconductor–ferromagnet– superconductor, superconductor–two-dimensional electron gas–superconductor junctions, and superconductor–con- striction–superconductor point contacts) were discussed in [8,9]. CPR manifestations related to unconventional sym- metry in the order parameters of a high-Tc superconductors were also widely investigated during last years [10–13]. As it follows from reviews [8–12] supercurrent SI dependence on the phase difference can be presented in general as 1 ( ) = ( sin cos ).S c n n I I n J n (2) The shape of supercurrent ( )SI does not only depend on temperature and the distance between electrodes, but also on the critical temperature and transport parameters of both superconductors and the interface layer in JJ structures. Detailed analysis of CPR in different JJ structures was car- ried out in [9]. The pairing symmetry in superconducting state also strongly influences on CPR [11]. Simple sinusoidal form of CPR (1) was widely used to study the dynamics and ultimate performance of analogous and digital devices based on JJ up to recent time [4–14]. Above mentioned reviews [8–12] have been devoted to the- oretical basis for the study of CPR in different Josephson structures. Results of these studies reveal fundamental phys- ical mechanisms for control and experimental investigation of CPR. It is clear that modification of CPR in different JJ structures leads to changing of dynamical properties of Jo- sephson circuits. Several recent research papers (see below) have been devoted to study dynamical effects in JJ with an- harmonic CPR. Recent progress in the theoretical study and experimental investigation of dynamical properties of such junctions justifies an overview of the fundamentals of JJ dynamics with anharmonic CPR. The main emphasis of this review is the investigation of CPR influence on dynamical properties of Josephson junc- tions. Firstly, we will briefly discuss influence of anisotro- py and multiband effects of the order parameter in super- conducting electrodes on the shape of CPR of JJ. The experimental investigations results concerning Josephson structures with anharmonic CPR are also reviewed. In se- cond section we present detailed results of study of anhar- monic CPR influence on I–V curve and on the plasma fre- quency of JJ. This section contains study of Shapiro steps in anharmonic JJ. Properties of long JJ with anharmonic CPR are also described in this section. Third section is devoted to detailed investigation of anharmonicity effects on characteristics of JJ qubits. Finally, conclusions are presented. 2. Influence of anisotropy and multiband effects of superconducting state on the CPR of JJ 2.1. JJ based on d-wave superconductors For the calculation of Josephson current in such struc- tures it is easy to use a Ginzburg–Landau theory of d-wave superconducting state based on its symmetry properties. Figure 1 presents schematic diagram of a JJ between pure 2 2x y d superconductors. The gap states are assumed to align with the crystalline axes, which are rotated on angles L and R with respect to the junction normals Ln and Rn on the left and right-hand sides, respectively. It is well known that d-wave order parameter symmetry was ob- served in cuprate superconductors [10–12]. In this sym- metry, we use a complex order parameter, which behaves the same way as the pair wave function [10] ( ) = cos cosx yk kk . (3) The Ginzburg–Landau free-energy functional F for d- wave superconductors has a form [15] 2 4 2 2 1= [ ( ) (| | | | )x yF dV A T K D D 2 2 1 | | ( 2 )] . 8 zK D B B H (4) Fig. 1. Schematic diagram of a JJ between d-wave superconductors. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 317 The real coefficients and iK are phenomenological parameters, and ( ) = ( )cA T T T changes its sign at the superconducting transition temperature Tc. The symbols D denote the components of the gauge-invariant gradient D 0[ (2 / )]iA , where A is the vector potential ( = ).B A For the calculation of the Josephson cur- rent, it is useful to introduce the coupling between the order parameters of two linked superconductors (Fig.1). Coupling between superconductors can be expressed through addition of term coup 1 1 2 2 1 2 2 1= ( ) ( ){ }F t dS n n , (5) where t is a real parameter denoting the coupling strength. The functions ( )j jn are symmetry functions of the inter- face normal vector jn in the crystal basis of the side j. For the current density perpendicular to the interface we can get 1 1 2 2 1 2 0 4 ( ) = ( ) ( ) sin . ct I n n (6) For the d-wave superconductors usage of symmetry func- tion as 2 2 1 1( ) = x yn nn [16] leads to final Sigrist–Rice result for clean JJ ( ) = cos(2 )cos(2 )sins L RI A , (7) where sA is a constant characteristic of the junction [12]. For the dirty limit of JJ the relation is: ( ) = cos2( )sin .s L RI A (8) Basing a Green's function method the Josephson current in a d-wave superconductor/insulator/d-wave superconduc- tor ( / / )d I d junction is calculated taking into account the anisotropy of the pair potentials explicitly [17,18] ____________________________________________________ /2 1 1 , ,/2 ( , , ) ( , , ) ( ) = | ( ) | | ( ) | cos ,N n n N L L L L n R kT a i a i R I d e (9) where 2 2 , , = ( ) .n L L n The quantity NR denotes the normal resistance and NR is expressed as /2 2 1 0 2 22 0 0/2 4 = cos ; = , (1 ) ( ) 4 cosh( )sinh N N N i i Z R d Z d Z d (10) _______________________________________________ 2 2 0 0 2 2 cos = 1 ; Z =cos 1 cos . (11) Here, N denotes the tunneling conductance for the in- jected quasiparticle when the junction is in the normal state. The quantity = 2 ( 1/2)n kT n denotes the Mat- subara frequency. The Andreev reflection [19] coefficient 1( , , )na i is obtained by solving the Bogoliubov equa- tion [21], and 1( , , )na i is obtained substituting , – ,L and – R for , ,L and R into 1( , , ),na i respectively. If we take only the = 0 component, the magnitude of the Josephson current is proportional to cos(2 )cos(2 ), and the phenomenological theory by Sigrist and Rice [16] is reproduced. In general, supercurrent in JJ with d-wave superconduc- tors ( )I can be decomposed into the series of sin ( )n and cos( )n using above presented Eq. (2). This equation includes the Josephson current component carried by the multiple Andreev reflection processes at the interface. In the above equation, the current components with index n correspond to the amplitudes of the nths reflection pro- cesses of quasiparticles. For ~ 0,N supercurrent ( )I is proportional to sin ( ) and the classical results of Ambreokar–Baratoff theory [22] are reproduced, while for = 1,N above Eqs. (5)–(11) reproduce the previous re- sults of Kulik and Omel’yanchuk theory [23,24]. On the other hand, for a fixed phase difference between two su- perconductors, the component of the Josephson critical current becomes either positive or negative depending on the injection angle of the quasiparticle (as it follows from Tanaka's analysis [17,19]). In some situations, the phase difference 0 , which gives the free energy minima, is lo- cated at neither zero nor . When the crystal axis is tilted from the interface normal, zero-energy states i.e. midgap states, are formed near the interface depending on the an- gle of the crystal axis and the injection angle of the quasiparticle. This effect leads to enhancement of the Jo- sephson current at low temperatures. Negative Josephson coupling was first noted by Kulik many years ago [3]. He discussed the spin-flip tunneling through an insulator with magnetic impurities. Late Bulaevskii et al. [20] proved that under some conditions such spin-flip tunneling prevails over the direct tunneling and leads to a -junction. The junction energy achieves minimum at the phase difference , and a spontaneous supercurrent may appear in a circuit containing the junc- tion. Two possible directions of the supercurrent reflect the doubly degenerated ground state. In contrast to the usual junction such a state is achieved without application of an external field. I.N. Askerzade 318 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 2.2. JJ between two-band superconductors Multiband superconductivity became a hot topic in condensed matter physics in 2001, when the two-band su- perconductivity in MgB2 with anomalous high = 39KcT was discovered [25]. It is striking that the pairing mecha- nism had electron-phonon origin in magnesium diboride and that order parameters, which are attributed to super- conducting energy gaps, have s-wave symmetry. Iron- based superconductors, which have been discovered not long ago, and nonmagnetic borocarbides [15,26] can be classified as multiband systems. In this section the station- ary Josephson effect in SCS (superconductor–constriction– superconductor) junction is presented. The behavior of such junctions even in the case of one-band superconductors, as revealed in [23,24], has the qualitative differences compar- ing to SIS (superconductor–insulator–superconductor) tun- nel junctions. The microscopic theory of the “dirty” SCS junction for two-band superconductors is built, which gener- alizes the Kulik–Omel’yanchouk theory in this case [27]. The case of dirty two-band superconductor with strong intra- band scattering rates by impurities (dirty limit) and weak interband scattering is investigated [27]. In the dirty limit superconductor is described by the Usadel equations for normal and anomalous Green's functions g and f, which for two-band superconductor take the form presented in [27] (Fig. 2). Calculation of the Josephson current between two- band superconductors in the absence of inter-band scatter- ing leads to: ____________________________________________________ 1 1 2 2 2 22 21 >0 1 1 2 2 2 2 2 22 22 >0 2 2 cos ( /2) sin ( /2)4 ( ) = arctan ( /2) ( /2)cos cos cos ( /2) sin ( /2)4 arctan . ( /2) ( /2)cos cos N N T I eR T eR (12) _______________________________________________ As it follows from Eq. (12) current flows independently from the first band to the first one and from the second band to the second one. This equation is a straightforward generalization of Ambreokar-Baratoff results for one-band superconductor [22]. Introducing the total resistance 1 2 1 2= /( )N N N N NR R R R R and normalizing the current on the value 0 = (2 / )N cI eR T the current-phase relations for different values of 1 2= /N Nr R R and temperature T are plotted in Fig. 3(a, b). Results of calculation of critical current temperature dependence for two-band based JJ are presented in Fig. 4. For the calculation of ( )I and ( )cI T the parameters for two-band superconductor MgB2 without inter-band interaction [15,27] were used. The deformation of ( )I curve depending on different parameters of JJ based on two-band superconductors is clear. Using perturbation theory in the first approximation for Green’s functions in each band for the case of nonzero interband scattering, the corrections to the current (12) 1 2=I I I were obtained [27]: ____________________________________________________ 2 12 2 1 1 1 2 2 3 2 2 2 22 21 1 2 1 2 2 1 2 2 2 2 2 22 1 1 2 2 ( e )cos ( /2) sin ( /2) = arctan ( ( /2)) ( /2)cos cos ( e )sin1 , 2 ( )( ( /2))cos i N i T I eR (13) 2 12 1 2 2 2 2 2 3 2 2 2 22 22 1 2 2 2 1 2 2 2 2 2 2 22 2 2 1 2 ( e )cos ( /2) sin ( /2) = arctan ( ( /2)) ( /2)cos cos ( e )sin1 . 2 ( )( ( /2))cos i N i T I eR (14) Fig. 2. Schematic diagram of a Josephson junction between two- band superconductors. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 319 where 12 is parameter of the interband scattering, and is a phase shift. When the interband scattering is taken into account and the phase shift 0, the phases of Green’s functions d0 not coincide with phases of order parameters .i From the above-mentioned discussion it follows that CPR of JJ based on two-band superconductors also devi- ates from simple sinusoidal form (1) (see Fig. 3). 2.3. CPR relation of JJ structures with FM and AFM layers In this part we pay attention to the approach based on the Usadel equation and consider the S/F/S junction with F layer of thickness 2df (Fig. 5). The following formula for the supercurrent was used in [8,28] ( ) = (0) f dF dF I ieN D TS F F dx dx , (15) where anomalous Green’s function ( )F x depends only on one coordinate x, and this function meets following condi- tions: /2 * 2 2 e ( , ) ( , – ) : ( ) = , i s fF x h F x h F d /2 2 2 e ( ) =s fF d , S is the junction cross-section area, and (0)N is the elec- tron density of state for one-spin projection. The last ex- pression gives the usual sinusoidal current-phase depend- ence with the critical current [28]: 2 2 2 2 2 / cosh (2 ) = (0) , tanh (2 ) (1 ) 2 f c f f k kd I eN D TS kd k k (16) where = / .B N sG Generalization of the presented theory on the case of the different interface transparencies is presented in [9,29]. It gives: 0 cos2 sinh(2 ) sin 2 cosh(2 ) = 4 cosh(4 ) cos4 c N V y y y y I y R y y , (17) where = ( / ) /(2 ),F F cy d H T H is the exchange energy in F layer. The S/F/S junctions reveal the nonmonotonic behavior of the critical current as a function of the F layer thickness. Vanishing of the critical current signals the tran- sition from the state 0 to the state . It occurs at 2 = 2.36cy which is exactly the critical value of the F layer thickness in the S/F/S multilayer system correspond- ing to the 0– -state transition (Fig. 6) [8,9]. CPR in different structures such as SFcFS and double- barrier SIFIS are presented in [30], where the non- monotonic temperature dependence of the critical current is analyzed. Deformation of CPR of double-barrier SIFIS junctions for different exchange integrals in F layer is pre- sented in Fig. 7. Similar change in CPR was experimental- ly observed in [31]. One of the interesting properties of SFS systems is the rotation of the magnetization vector of F layer under action of an external magnetic field [32–34]. Details of CPR of different Josephson structures with F Fig. 3. CPR of MgB2/MgB2 junction for different temperatures T: 0(1); 0.5Tc(2); 0.9Tc(3) and ratios of resistances r = RN1/RN2. Fig. 4. Temperature dependencies of critical current Ic for differ- ent values of r = RN1/RN2: 0.1(1); 1(2); 10(3). Fig. 5. Schematic description of S/F/S junction. I.N. Askerzade 320 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 layer were presented in excellent reviews [8,9]. The study of the CPR is also important for understanding the funda- mental properties of superconducting materials, such as symmetry of the superconducting correlation and peculiari- ties of the spin transport in multilayer systems based on superconducting and ferromagnetic materials. Despite wide discussion about JJ with FM layers, there are few papers concerning investigations of structures with AFM layers. Firstly such structure was studied by Gor’kov and Kresin [35]. They found that the critical current strongly depends on external magnetic field. The analytical expression can be written as 0 2 ( ) = cos 4 c s c s s I M I M M , (18) where 1 is related to characteristic of AFM layer, 0 < < 1sM is parameter of AFM ordering, 0cI is critical current in the absence of external magnetic field coinciding with corresponding critical current in SNS junctions. It is useful to note the importance of study of JJ with magneti- cally ordered layers. As mentioned in [5], such Josephson structures may allow substantial savings in the Josephson circuit area. 2.4. Experimental results of CPR investigations in different Josephson structures As it follows from above presented theoretical review, the general case CPR in Josephson structures is determined by the types of JJ. At high temperatures ( << )c cT T T de- viation of CPR ( )I from sin law is negligible for any type of JJ. At low temperatures ( << )cT T the relation ( ) sinI takes place for SIS junctions [36]. In early in- vestigations [36], the high accuracy realization of sinusoidal character of CPR was shown using plasma resonance tech- nique. Recently, Gronbech-Jensen et al. [37] studied the dynamics of the tunnel JJ simultaneously carrying dc and ac currents by measuring the statistics of switching of low- temperature Nb–NbAlOx–Nb type tunnel junctions to the resistive state. The critical current statistics in this system, which is controlled by thermal fluctuations at the bottom of the potential well ( ) = ( 1 cos ),JU E i was deter- mined for 10000 events. By changing the amplitude of ac current, it was possible to control the dc current correspond- ing to a peak in the switching events distribution. A new method for CPR measurement and some of its practical applications were presented in [38,39]. Most commonly for the experimental investigation of the CPR, the weak link of interest is incorporated in a superconduct- ing ring with a sufficiently small inductance L. This circuit is usually called a single-junction interferometer [4]. Under limitations / << 1,NL R and 2 << 1LC the supercon- ducting part ( ) = ( )s cI I f of the current exceeds essen- tially all other components, so the following equation is valid for single junction interferometer [38,39]: = ( ),e lf (19) where l is the normalized inductance, 02 / .cl LI There is a more precise method to determine the CPR using radio frequency (rf) technique. It was proposed many years ago [40,41]. Further development of this method was presented Fig. 6. Critical current of S/F/S junctions versus =y / /(2 ),F F cd H T where H is the exchange energy. Fig. 7. Deformation of CPR of SIFIS junction for different ex- change energies. Fig. 8. Experimental CPR of symmetric /4 grain-boundary junction. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 321 by Ii’ichev et al. in [42]. They have shown that the CPR and the phase-dependent conductance can be extracted from experimental data. Results of measurements of Jo- sephson current through a junction as a function of the phase difference in symmetric 45 grain-boundary high- Tc junction are presented in Fig. 8 [43]. Recent achieve- ments in fabrication of the JJ based on high-Tc superconduc- tors were described in [44]. Measurements reveal that YBCO-based grain boundary tunnel junctions fabricated in [44] are highly hysteretic and Fig. 9 shows the ratio of coef- ficients 1I and 2I determined by a Fourier analysis of the CPR at various temperatures. With decreasing T, value of 2I grows monotonically down to = 4.2K,T while the 1I component exhibits only a weak temperature dependence [44]. Very recent review of physical properties of JJ based on high-Tc superconductor was presented in [45]. Further- more anharmonic CPR in graphene JJ was reported recently in experimental research [46] and corresponding theoretical calculations were proposed in [47]. Very recently, topological insulators attached to super- conductors have attracted great interest of researchers. The topological insulator offers a new state of matter, which is topologically different from the conventional band insula- tor [48–50]. When SF junctions are deposited on a topo- logical insulator, surface Dirac fermions gain a domain wall structure of the mass. The CPR shows 4 periodicity, i.e., the shape of supercurrent has a form of sin ( /2) [51,52]. JJ in hybrid superconductor-topological insulator devices revealing two peculiarities was reported in [53]. c NI R products for this structures is inversely proportional to the width of the junction. Another property is related to a low characteristic magnetic field needed for suppression of supercurrent, i.e., Fraunhofer capture is different from traditional dependence ( )cI H [4]. The shape of CPR for such a junction is presented in Fig. 10. Detailed analysis of the superconductor-topological insulator junctions is the subject of future investigations. 3. Influence of anharmonic effects of CPR on JJ dynamics 3.1. Anharmonic effects in I–V curve For a long period, the real shape of the CPR was not considered as an important factor affecting dynamical properties of JJ. Tunnel Josephson junction of SIS struc- ture reveals ( ) = sin ,SI which was observed experimen- tally with high precision for such junctions (see above). The shape of the CPR, or more explicitly the energy and phase dependencies of spectral current density have be- come important parameters in the analysis of the dynamic properties of Josephson junction circuits. Small deviation from harmonic case does not essentially affect the response of the junctions on a steady magnetic field and may be taken into account in the circuit design as an additional intrinsic inductance (see [54]), which must be added to the geometrical one in the circuit simulation. In this section, we study I–V curve of JJ with considerably anharmonic CPR using relation = (sin sin 2 ).J cI I The resistive- ly, capacitively, inductively shunted Josephson junction (RCLSJ) circuit shown in Fig. 11 is shunted by a small external resistor isatisting s nR R [4,55,56]. Here nR and sR denote the normal state and shunt resistances, re- spectively. As shown in the Fig. 11 the Josephson tunnel junction is replaced by three parallel current channels. The total current through JJ is represented as a sum of the supercurrent ( ),I the displacement current =DI ( / ),C dV dt and the normal current due to quasiparticles Fig. 9. YBCO based grain boundary junction: I2/I1 versus tem- perature. . Fig. 10. CPR of superconductor-topological insulator junction. Fig. 11. Circuit model of RCLSJ. I.N. Askerzade 322 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 = / ( ).NI V R V The voltage-dependent junction resistance [4,55] is assumed to be: sg if | | > , ( ) = if | | . n g g R V V R V R V V (20) where = 2 /gV e is the gap voltage that depends on the energy gap (i.e., ) of superconductor, nR is the normal state resistance and sgR is the sub-gap resistance of the JJ in the superconducting state. The applied bias current dcI is carried by the sum of the listed components ( , , ).J N SI I I = (sin sin 2 )J cI I , = / ( )NI V R V , = ( / ).DI C dV dt = D N J sI I I I I where sI denotes the current in the shunt branch. For simplicity, we ignore the effect of ther- mal noise throughout this study fluc( = 0).I Equations that correspond to the circuit in Fig. 11 in dimensionless form are = d d v , ( ) ( ) = ,C s d g f i i d v v v (21) = ,s L s di i d v where 2= (2 / )C c se I CR is the McCumber capacitance parameter; ( ) = / ( )sg R Rv v is the normalized tunnel junction conductance; = /s s ci I I is dimensionless shunt current; = / ci I I is dimensionless external dc bias current; = (2 / )L c se I L is the dimensionless inductance; = ct is the normalized time, = (2 / )c ce V is the characteristic frequency, and =c c sV I R is the characteristic voltage. The relationship between C and c can be written as 2= ( / (0))C c p where plasma frequency (0) =p 2 / .ceI C The solutions of Eqs. (21) are numerically obtained using MATLAB routine based on adaptive Runge–Kutta method [57]. The time-averaged voltage for the determination of I–V curve can be evaluated using the expression: 0 1 = / = ( ) rng rng d d dv v , (22) where rng is the sampling range. Note that rng in Eq. (22) is taken much longer than the period of Josephson oscillations as well as relaxation oscillations. For that rea- son, the time-averaged voltage in Eq. (22) is sometimes called in literature as long-time averaged voltage. In order to study the influence of second harmonic on the dynamics of the JJ, we firstly evaluated the critical cur- rent related to the amplitude of both harmonics. In such way, the normalized critical current can be found as an extremum of the function ( ) (sin sin 2 )f 0 / = max( ( ))c cI I f , (23) where 0c I is the critical current at = 0. The normalized critical current with respect to anharmonicity parameter is plotted in Fig. 12. As shown in the figure, cI is nonlinear for small , whereas it is linear for large values. Moreo- ver, the linear dependence of critical current cI was exper- imentally observed at large in YBCO-based JJ [43]. In addition, a similar plot in Fig. 12 was obtained using analyt- ical expression for critical current given in [58]. Two types of dynamics of RCLSJ circuit presented in Fig. 13 can be explained using load-line analysis associat- ed with I–V curve of the JJ. The first case is shown in Fig. 13(a) and corresponds to relaxation oscillations in the circuit with parameters =1.1i , 0 = 1.11C , 0 = 21.7L at = 0. Relaxation oscillations in Josephson circuits have been studied by many authors [55] and [59]. A similar re- laxation generator was used to study the dynamical proper- ties of tunnel JJ comparator in [60]. The second regime corresponds to the regular ac Josephson oscillations [55] and it is shown in Fig. 13(b) with parameters =1.1i , 0 = 2.22C , 0 = 43.4L , at = 0 . For nonzero anhar- monicity parameter such as = 0.4 (see Fig. 13(c)), the amplitude of the Josephson oscillations becomes smaller, which is related to the effective capacitive properties of JJ. Such situations can be explained by the increase of the critical current of JJ with anharmonic CPR (the detailed discussion is given below). Fig. 12. (Color online) Normalized critical current versus anharmonicity parameter . Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 323 In paper [57] numerical analysis of I–V characteristics for different values was performed as shown in Fig. 14. In the figure, we have plotted I–V characteristics of the system with different 0C and 0L values using the same ,sR sg ,R and nR from Table 1, similar [55]. Note that 0C and 0L refer to the harmonic case of the CPR (i.e., = 0). Similar results were obtained in [61] for = 0.2 case only due to the limited nature of the analytical calcu- lations. Furthermore, it is difficult to study directly the details of the dynamics both experimentally and analytical- ly, therefore, we can rely on numerical solutions of Eqs. (21) to study the influence of anharmonicity parame- ter . As can be seen from Fig.14, the width of the hystere- sis in the I–V curve becomes larger with an increase of anharmonicity parameter . Consequently, the presence of anharmonic CPR impacts the inertial properties of the JJ as an undesirable effect. In addition, we repeat few simula- tions using opposite sign of the anharmonicity parameter in relation to our calculations presented here. We observed that the hysteresis of the I–V characteristics decreases compared to its counter part in the presented plots. In gen- eral case, the sign of is determined by the physical prop- erties of barrier layer in Josephson structure [10,20,58]. The size of hysteresis in I–V curve is characterized by the return current, at which the JJ switches from R-branch to S-branch in the I–V curve. The relationship between the return current and high values of McCumber parameter C can be obtained using simple resistive model [4]: 4 1 = .R c C I I (24) If we consider Eq. (20), the return current vs McCumber parameter qualitatively reveals a similar be- havior [4]. The deviation from the expression in Eq. (24) becomes larger when the ratio of sg / nR R increases. On the other hand, the return current RI is not only a function of Table 1. Fabrication parameters of Josephson junctions (see [55]) T, K Ic0, mA Vg, mV Rsg, Rn, R, 4.22 0.550 2.91 50 3 1.1 7.60 0.275 2.09 15 3 1.1 Fig. 13. (Color online) Time dependence of dynamical variables: voltage d /d and current I through shunt branch. Computational parameters are: i = 1.1, C0 = 1.11, L0 = 21.7, = 0 (a); i = 1.1, C0 = 2.22, L0 = 43.4, = 0 (b); i = 1.336, C0 = 2.696, L0 = = 52.701, = 0.4 (c). Fig. 14. (Color online) I–V curves for various values at C0 = 10; L0 = 1 (a); L0 = 10(b); L0 = 30 (c). I.N. Askerzade 324 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 C but also a function of and L . However, it is diffi- cult to obtain an explicit analytical expression for it. For this reason, numerical simulations are performed to ana- lyze the influence of anharmonicity parameter and di- mensionless inductance L on the normalized return cur- rent /R cI I at two different values of McCumber parameter (e.g., 0 = 5C and 0 =10).C First of all, we will discuss the relationship between /R cI I and which is shown in Fig. 15 for various 0L values. In general, the influence of the capacitance and inductance of the JJ on the junction impedance is of oppo- site character. That is why one reactive element will damp the influence of the other. This implies that corresponding I–V curve and associated hysteresis will be determined by the resulting impedance. At fixed 0L , the value of the Josephson inductance = ( /2 )/c cL e I decreases with increasing. As a result, the influence of the junction capaci- tance at nonzero on the I–V curve becomes dominant compared to harmonic case. If we compare the plots here with the results in [61], the normalized return current / ,R cI I is defined here accurately in contrast to the result therein. The reason is that the author in introduced [61] an approximate solution using analytical approach. The exact value of return current is sensitive to the characteristics of the junction in the subgap region. Usually a switching from R-state to S-state leads to an exponential decay of the voltage transient waveform. As mentioned in [4], the voltage transient from R-state to S-state is accom- panied by a slowly damped plasma oscillation. For this reason, we observed inaccuracies at some points on the curves presented in Fig. 15. The accuracy of our calcula- tions for the return current in Fig. 15 was roughly estimat- ed as 5%. The relationship between return current /R cI I and di- mensionless inductance L is illustrated in Fig. 16 for var- ious . The junction circuit shown in Fig. 11 is shunted by a serially connected inductance sL and shunt resistor sR . This means that the junction is shunted by impedance 2 = 1 .s s s s Z L R R (25) At vanishing shunt inductance (i.e., sg ),s sL R R we come to standard resistively shunted junction (RSJ) Fig 15. (Color online) Return current dependence on anhar- monicity parameter , at C0= 5 (a); C0 = 10 (b). Fig. 16. (Color online) Return current dependence on dimension- less inductance L0 at C0= 5 (a); C0 = 10 (b). Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 325 model with hysteresis on I–V curve controlled by McCumber parameter 2= (2 / ) .C c se I CR With increasing inductance sL the impedance sZ also increases. On the other hand, if the shunting effect is in the high shunting inductance limit (i.e., )s sL R the impedance sZ ap- proaches .sL In this case, the impedance sZ becomes much greater than sgR and nR (i.e., sg ).s nZ R R As a result, McCumber parameter C can be determined by sub-gap resistance sg :R 2 sg sg( ) = (2 / ) .C cR e I CR Due to that reason, sg( )C R will become greater than .C The return current /R cI I approximately reaches the constant values lower than corresponding value for .s sL R It is shown in Fig. 16, that the crossover from one regime to another reveals a peak character. Furthermore, as it follows from Fig. 16, peaks width increases for large McCumber parameter .C The inaccurate behavior similar to that in Fig. 16 is also observed on the curves in Fig. 15 due to the transient plasma oscillation in R → S switching. 3.2. Plasma frequency of JJ with anharmonic CPR It is useful to discuss the influence of CPR anhar- monicity on small perturbations of the S state of JJ, i.e., the possible phase motion in the vicinity of equilibrium state 0. It is known, that JJ dynamics has much in common with the motion of a particle in potential of the washboard type [4] ( ) = (cos 1)jU E i , (26) where i is the dc current expressed in the cI (critical cur- rent) units, is the Josephson phase, and = /2j cE I e is the Josephson energy. If the capacitance of the junction is sufficiently large, the junction may exhibit slowly decay- ing oscillations of the plasma phase at the bottom of the potential well (26). The frequency of these oscillations (plasma frequency) depends on the dc current and is given by formula (see, e.g., [4]), 1/2 2 1/42 = (1 )c p eI i C . (27) Relation (27) is usually satisfied for the JJ connected to a dc voltage source. If = sin ,cI I the theory exhibits per- fect agreement with experiment [36]. However, there are deviations from the behavior predicted by Eq. (27) in the JJ characterized by anharmonic CPR. The anharmonicity may be caused by the simultaneous passage of both dc and ac currents of large amplitudes via the junction. Re- cently, Gronbech-Jensen et al. [37] studied the statistics of S → R switching of low-temperature tunnel JJ of the Nb–NbAlOx–Nb type. The critical current in this system was determined for 10000 events. The obtained results confirms the validity of relation (27) for the plasma frequency for small amplitudes of the ac current component. However, as the ac current ampli- tude grows, the agreement of formula (27) with the exper- imental values measured deteriorates, which can be related to the anharmonic character of the potential ( ) = (cos cos2 1)jU E i at large ac current amplitudes. The theoretical investigation of the alternating current effect on the plasma frequency of the tunnel JJ simultaneously carrying dc and ac currents is presented below. The dynamics of a JJ can be described using the following equation (in this equation we use time units = (0) ):p t 1 sin sin 2 = sind di t . (28) For the calculation we will use 0 1= , where 1 obeys equation 1 = sind di i t . (29) Using mathematical expressions described in [62] 2cos ( sin ) = exp( ); = ( )n n ka t A in t A J a , (30) 2 1sin ( sin ) = exp( ); = ( )n n ka t B in t B J a (31) we obtain the following expression for plasma frequency of JJ with anharmonic CPR 2 pl 0 0 02 pl ( ) = cos 2 ( )cos 2 (0) a J a . (32) In the last expression 0 ( )J a is the Bessel function of zero order, (0) = 2 / ,p ceI C 2 2= /( ).d da i Equi- librium value 0 is determined from relation 0 0 0 0 = sin sin 2 ( ) i J a . (33) According to Eq. (32), an increase in the ac current compo- nent di results in decrease in the plasma frequency .p Thus, the presence of the ac component leads to renormaliza- tion of the plasma frequency (27) of the tunnel JJ. The results of calculations according to Eqs. (32) and (33) are presented in the Fig. 17 by the solid and dashed curves, respectively, and compared with the experimental data (black circles) taken from [37]. Result of calculations of 2 2 pl pl( )/ (0) as function of anharmonicity parameter is presented in Fig. 17. Nonsymmetric character of 2 pl ( ) is clear from calculations for different values of a. There is a minimum of 2 2 pl pl( )/ (0) 0.794 at negative = 0.3 [63]. At positive values of anharmonicity parameter plas- ma frequency 2 pl ( ) decreases with increasing amplitude of oscillating part .di At negative values of anharmonicity parameter influence of a on the plasma frequency 2 pl ( ) is very small. Results of calculations of 2 pl ( )a at different anharmonicity parameter are presented in Fig. 18. At small , the change in plasma frequency 2 pl ( )a is negli- I.N. Askerzade 326 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 gible, while at high the influence of anharmonicity is important. At negative influence of anharmonicity of CPR on plasma frequency is decreased. 3.3. Shapiro steps in I–V curve of JJ with anharmonic CPR When radio-frequency signal is applied to Josephson junction, its I–V curve shows a set of Shapiro steps result- ing from phaselocking of Josephson oscillations [64]. Ana- lytical description of the Shapiro step dependence on the signal amplitude was obtained only for a high-frequency limit in the frame of RSJ model describing an overdamped junction with McCumber parameter << 1C [4]. In par- ticular, a nonsinusoidal CPR results in the generation of subharmonic Shapiro steps [65], which may lead to insta- bilities in modes of operation of Josephson voltage stand- ards. Results of analytical and computational investigations of high-frequency dynamics of JJ characterized by nonzero capacitance ( > 1)C and the second harmonic in the CPR are presented in [66]. Above presented Eq. (28) gives the result for step amplitude in harmonic case ( = 0) 2 = 2 ( ) 1 n n C a i J , (34) where ( )nJ x is the Bessel function, a and are the am- plitude and frequency of applied rf signal. The case of = 0C coincides with the well known RSJ model [4]. In contrast to harmonic case ( = 0),C there are subharmonic steps in I–V curve with amplitude (according to [66]) 1 2 2 (2 1)/2 2 ( ) 1 ( ) 1 = 2 ( ) /4 1 n n C C n C a a J J i . (35) For JJ with anharmonic CPR ( 0) the following ex- pression for harmonic Shapiro step amplitudes is obtained as [66]: ____________________________________________________ 2 2 2 = 2max sin sin 2 ( ) 1 ( ) 1 n n n C C a a i J J , (36) and for subharmonic steps as 1 0 2 2 1/2 1 2 2 0 2 2 2 2 2 2 ( ) 1 ( ) 12 = 2max sin ( ) 1 ( ) /4 1 2 2 ( ) 1 ( ) 1 4 cos . ( ) 1 C C C C C C C C C a a J J a i J a a J J (37) Fig. 17. Plasma frequency of JJ as function of anharmonicity parameter. Fig. 18. Plasma frequency of JJ as function of amplitude of ex- ternal ac current for different anharmonicity parameter. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 327 Figures 19 and 20 present the analytical results, as well as experimental data for both c-oriented and c-tilted Nb/Au/YBCO junctions formed on NdGaO substrates (junc- tion areas ranged from 10·10 m 2 to 30·30 m 2 ) [67,68]. Similar results for subharmonic Shapiro steps were obtained in [69] for c axis YBa2Cu3O7–x/Pb tunnel junctions. Fig. 19. Dependencies of the 1/2- and 3/2-step amplitudes on the applied signal amplitude a at frequencies = 0.611, = 35 and = 0. Solid line corresponds to Eq. (35), filled dots correspond to numerical simulation, and empty dots correspond to experimental results for the c-oriented Nb/Au/YBCO junctions (a). Dependencies of the critical current amplitude i/2 (0-step) and the 1-step amplitude i (in inset) on the applied signal amplitude a at frequency = 1.62 and = 4. Dashed and solid lines correspond to formula (36) at = 0 and = 1, the filled dots correspond to experimental results for the c-tilted Nb/Au/YBCO junctions (b). Fig. 20. Dependence of the 1/2-step amplitude i on the applied signal of amplitude a at = 4 for frequencies = 1.62 (a) and = 2.2 (b). Dashed, solid and dotted lines correspond to the step behavior according to formula (37) with = 0, = 0.14, and = 0.3, respectively. The filled dots are experimental data for the c-tilted Nb/Au/YBCO junction. I.N. Askerzade 328 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 3.4. Inluence of anharmonic CPR on long JJ dynamics Physical properties of magnetic flux dynamics in long JJ play an important role in the modern superconductivity related electronics. We consider a long JJ, where the word “long” means that we take into account the variation of the phase along one of the spatial coordinates, i.e., along x. Further, it will become clear that opposite to the case of the usual JJ with only first harmonic in CPR, there is no uni- versal length scale at which the phase changes or at which the weak magnetic field is screened. Moreover, depending on the state, the characteristic scale of x variation affecting magnetic field screening can be different, so the junction can be small if it is in one state and it can be long in anoth- er state. At the same time, in order to neglect the spatial variation of the phase along the junction width (y direc- tion), we assume that the junction is short in the y direction in all states. The calculation of static magnetic flux distri- butions in the long JJ with consideration of the anharmonic CPR was carried out in [58,70–72]. This model is de- scribed by the double sine-Gordon equation (2SG) for magnetic flux distribution in the static regime sin sin 2 = ; ( , )x l l (38) with the boundary conditions in the following form ( ) = el h . (39) The magnitude is the external current, l is the semilength of the junction. cI and are parameters cor- responding to contributions of 1st and 2nd harmonic, re- spectively. he is external magnetic field. Stability analysis of ( , )x p is based on numerical solution of the corre- sponding Sturm–Liouville problem ( ) = ; ( ) = 0q x l , (40) with potential ( ) = cos 2 cos 2 .q x x x The minimal the eigenvalue 0 ( ) > 0p corresponds to the stable solution. In case when 0 ( ) < 0p the solution ( , )x p is unstable. The case when 0 ( ) = 0p indicates the bifurcation with respect to one of parameters = ( , , , ).ep l h Results of investigations carried out in [70–72] shows that considera- tion of the second harmonic significantly changes the shape and stability properties of trivial and fluxon static distribution in long JJ. In the “traditional” case = 0 two trivial solutions = 0 and = (denoted by 0M and ,M respectively) are known at = 0 and 0.eh Consideration of the se- cond harmonic sin 2 leads to appearance of two addi- tional solutions = arccos( 1/2 ) (denoted as M ).ac The corresponding 0 as functions of 2SG-equation coeffi- cients have the form 0 0[ ] =1 2 ,M 0[ ] = 1 2 ,M and 2 0[ ] [1 (1/2 ) ].M ac The exponential stability of these constant solutions is determined by the signs of the parameters and by the [70–72] (Fig. 21). The full energy associated with the distribution of ( )x is calculated using the expression: 2 ( ) = 1 ( ) 2 l e l F p q x dx h , (41) Fluxon solution of Eq. (38) in the case of = 0eh and = 0 at l has a form [73]: = ( ) = 4arctan(exp( )) 2x x n (42) where “+” sign corresponds to fluxon, “–” sign corre- sponds to antifluxon. At small external fields eh such dis- tributions are fluxon 1, antifluxon 1 and their bound states 1 1 and 1 1. As external magnetic field he grows, more complicated stable fluxon and bound states appear: n and nn ( =1,2,3,...).n The energy of one-fluxon distribution 1 converges to unity ( 0) 1F which corresponds to an energy of a single fluxon 1 in a traditional “infinite” junction model at = 1. With change of the number of fluxons 1 ( ) = ( ) 2 l l N p x dx l (43) corresponding to the distribution 1 is conserved, i.e., / 0.N Here we have 1[ ] = 1N . Results of influence of second harmonic CPR in 0( )eh were calculated in [70–72] and presented in Figs. 22, 23. Simulation results show that consideration of the second harmonic in CPR Fig. 21. Stability region as a function of anharmonicity parameter. Fig. 22. Dependence of 0(he) for 1 with increasing of anharmonicity parameter . 2l = 10, = 0. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 329 significantly changes the shape and stability properties of fluxon static distribution in long JJ. 4. Qubits based on JJ with anharmonic CPR 4.1. Qubits The great majority of Josephson and SQUID research since the beginning of the XXI century has focused on possible applications in the field of quantum computation [74,75]. In classical digital computation, the processor takes as its input ones and zeros (coded, in the case of sili- con integrated circuits, as two distinct voltage levels) and derives an output by performing some kind of classical Boolean logical operation on this input. In contrast to it, in quantum computation the processor takes as its input a quantum coherent superposition of ones and zeros [74,75]. The quantum processor then performs a quantum mechani- cal operation on this input state in order to derive an output which is also a quantum coherent superposition. The basic element of a quantum computer is known as a qubit. The state of the qubit, | is a linear superposition of the two quantum basis states | 0 and |1 [74,75]. Realization of qubits based on JJ and their application requires the millikelvin temperature region. As follows from above presented discussion, the anharmonic character of CPR becomes important at this temperature and therefore anharmonicity must be taken into account in discussion of JJ qubits. This conclusion is also supported by investiga- tions [44,76]. In order to analyze the qubits with JJ, one has to solve the corresponding stationary Schrödinger equation with an appropriate boundary condition =H E , (44) where H is the Hamiltonian operator, is the wavefunction, and E is the eigenenergy. Quantum dynam- ics of an isolated JJ is described with the Mathieu–Bloch picture for a particle moving in a periodic potential, similar to the electronic solid state theory [4]. In this section, we shall describe the quantum dynamics of two types of qubits: phase and charge qubits. Such qubits have distinct limiting regimes: the phase regime ,j cE E is analogous to the tight-binding approximation, and the charge regime, ,j cE E is analogous to the near-free particle approxi- mation. At the end of this section, we also shall discuss a flux qubits using low inductance interferometer with an- harmonic JJ [77,78,80,90]. As mentioned in previous studies (i.e., [4, 81,82]), the wavefunction should satisfy the periodic boundary condi- tion ( ) = ( 2 ). Therefore, the required boundary condition for solving Eq. (44) can be expressed as ( ) = ( ), ( ) = ( )a b a b , where min=a and min= 2b are the lower and up- per bounds such that a and b depend on the variation of bi as well as . Note that the value of a and b are different for phase and charge qubits. Additional details about a and b are given below. 4.1.1. Phase qubit with anharmonic CPR. A circuit model of a phase qubit system using single JJ is shown in Fig. 24. Corresponding Hamiltonian of the system [81,83] associated with anharmonic CPR can be written as [82] 2 2 = [ cos cos 2 ] 2 c j bH E E i , (45) where = /b b ci I I is the ratio of the bias currents applied to the system, denotes the phase difference, cE is the elec- trostatic energy, and jE is the Josephson coupling energy. In some models suggested in [78] and [80], CPR of Joseph- son junctions includes second and third harmonics. The presence of second harmonic in CPR leads to hump like shape of potential energy which seems to be very im- portant for the manipulation with phase qubit. Figure 25 illustrates the influence of second harmonic on the potential Fig. 23. Dependence of 0(he) for one fluxon states 1 and 1* with increasing of anharmonicity parameter . 2 l = 10, = 0. Fig. 24. Circuit model of a phase qubit. The crossed lines indicate the junction. Ib is the bias current source. I.N. Askerzade 330 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 ( ) = 1 cos( ) cos(2 ) 2 2 U , (46) for various values of . For instance, the potential has a single minimum at = 0 for 0.5. and double minima for > 0.5 in the ranges < < 0 and 0 < < , re- spectively. The authors in [58] and [84] also discussed how ( )U changes from single potential well to double poten- tial well in the case of junctions (i.e., the junctions with negative critical current). After substituting Eq.(45) into the Schrödinger Equa- tion (44), we can obtain Mathieu eigenvalue equation for zero bias current case: 2 2 cos cos 2 = , 2 j c Ed Ed (47) where = / .cE E Equation (47) is called the Mathieu ei- genvalue equation, it describes the properties of phase qubit under the periodic boundary condition with lower bound = 0a and upper bound = 2 .b 4.1.2. Charge qubit with anharmonic CPR. A circuit model of a charge qubit system using single JJ is shown in Fig. 26. The Hamiltonian of the charge qubit system [81,83] with anharmonic CPR can be written as 2ˆ= ( ) cos cos 2 , 2 c g j bH E n n E i (48) where 2= /(2 )c gE Q C is the electrostatic energy (Cooper pair charge energy) that depends on gate voltage gV and the capacitor = ,g jC C C and = /(2 )j cE I e is the Joseph- son coupling energy in terms of critical current of Josephson junction .cI Introduced ˆ = ( / )n i is the dimensionless momentum operator that refers to the number of Cooper-pair on the island and has a physical meaning of charge Q ac- cumulated on the junction capacitor jC in the units of dou- ble electronic charges (i.e., ˆ ˆ= 2 ).Q en Furthermore, = / (2 )g g gn C V e is the dimensionless charge number used to externally control the system [85]. Figure 26 illustrates a single Cooper pair box for a charge qubit including a gate voltage gV and a gate capacitance .gC Using washboard potential from Eq. (46) for nonzero bias current as well as , we can determine the upper and lower bounds of the periodicity interval finding roots of equation ( ) = = sin sin 2 = 0b dU f i d that sets condition for ( )U stable minimum min . In this case, the interval for periodic boundary will be min=a and min= 2b . Periodical solutions in the case of non- zero bias current were discussed in detail in [4] and [82] using wavepacket approach. After substituting Eq. (48) into the Schrödinger equa- tion as in Eq. (44), we can obtain a Mathieu-type eigenval- ue equation: 2 2 = , d d p q dd (49) where = / ,cE E the terms = 2 gp in and 2| | ( ) = cos cos 2 2 4 j b c E p q i E . Here, we will present the evaluation of expectation values of the supercurrent operator given in equation ˆ / =s cI I sin sin 2 and the number operator ˆ = ( / )n i within the interval [a,b] in the lowest band for the charge qubit. First of all, the expectation value of supercurrent [86] can be obtained from Fig. 25. Potential energy U( ) of anharmonic JJ. Fig. 26. Circuit model of a charge qubit. The crossed box indicates the combination of the tunnel element and the junction capacitor Cj connected parallel. The gate charge is Qg = 2eng = CgVg. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 331 1ˆ= | / | = {sin sin 2 } . b s s c a i I I d b a (50) Similarly, the expectation value of number operator n̂ can be determined as 1 ˆ ˆ= | | = b a n n d b a . (51) The Mathieu-type eigenvalue problems defined in Eqs. (47), (49) can be discretized using the finite difference approach discussed in [81] on a discrete lattice: 1 1 = , = 0,1,2,..., 1.j j j j je f e j N The problem is that we want to get rid of the upper and lower end wavefunctions 1 1( = N and 0= )N in the form of boundary conditions given in Eq. (44). After that, through mathematical discretization of these equa- tions we can approximate the continuum behavior of the system to obtain the eigenvalue problem of the form: 0 = , = 0,1,2,n n n nA , (52) where n is an eigenfunction associated with eigenvalue n for an arbitrary eigenstate n; and 0A is a complex N N periodic tridiagonal coefficient matrix, 0 1 2 3 0 4 2 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 = 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N f e e e f e e f e e f e e f f e e e f A (53) The coefficients of the periodic tridiagonal matrix in Eq. (53) are: 2 2= 1 /2, = ( 2), = , = , 1 j j b a e hp f h q h h N (54) where e is the complex conjugate and h is the step size in the discretization scheme. Throughout this study, the numerical solution of Eq. (52) is calculated using the conventional LAPACK eigenvalue solver. Note that the coefficient matrix in Eq. (53) requires an N + 2 data storage space in its present form. In the litera- ture ([87] and [88]) the linear system solution with a real symmetric periodic tridiagonal coefficient matrix is widely studied, but the eigenvalue problem [81] formulated in the present study requires an efficient design and stable algo- rithm for finding the eigenvalues of such a matrix. The number of subintervals is preferred to be N = 3000 with suf- ficient accuracy, the reason and preference of it will be ex- plained. 4.2. Influence of anharmonic CPR on qubit characteristics 4.2.1. Phase qubit. The analysis in [78] was limited to asymptotical solutions of Mathieu equations. Here, we per- formed a full numerical analysis of Mathieu equation (47) with inclusion of second harmonic in phase qubit regime (i.e., / 1).j cE E As follows from the results, all energy levels split into two sub-levels = .i i i Energy spec- trum of Mathieu equations for = 0, 1i evaluated using nu- merical calculations presented in Fig. 27 coincides with the results in [78]. The ground ( = 0)i and first ( =1)i states of the energy spectrum were obtained and it is shown that split- ting in the ground and first excited state depends on the anharmonicity parameter . For high values of energy scale /2 ,j cE E the splitting between = 0 and 0 cases be- comes large. On the other hand, it can be seen from the cal- culations that the change in splitting of ground state is Fig. 27. (Color online) Splitting parameters versus anhar- monicity of the CPR. Splitting of the ground state (a), first excited state (b). I.N. Askerzade 332 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 smaller than the change of the first level. This means that the first state is more sensitive to anharmonicity parameter . Furthermore, the numerical modeling is carried out to an- alyze the influence of the control parameters on the splitting of energy states = .i i i Figure 27 presents the behav- ior of the splitting of energy states i for various energy scales / .j cE E The results for 0 are presented in Fig. 27(a) within the range 0 2. As was mentioned before, the authors in [78,89] found similar results for dc-SQUID from an oscillatory model analytically. Unlike our results, their findings are limited to the range 0.5 1.5 for 0. In contrast to [78,89], we observed fine structure in dependence of 0 ( ) for different /j cE E values. For small anhar- monicity parameter (i.e., < 0.65), the splitting parameter i decreases linearly with increasing . The results for i are in good agreement with findings of solid state theory. Fixing the amplitude of first harmonic by negative sign of second harmonic leads to an approximate linear decreasing of 0 ( ) (1 )jE [90]. Similar behavior of linear de- creasing in 0 is obtained in our numerical results presented in Fig. 27(a). However, compared to approximate result, the vanishing point of 0 is located in the range 0.6 < < 0.9 for various energy scales. This is because numerical results are more precise than the results obtained from preceding approximate expression. In addition, ( , )U in Fig. 25 has a single minimum for 0.5 while it has two minima for > 0.5. As discussed before for Fig. 25, the shape of the potential was switched from a single well to a double well structure for > 0.5. For higher values of energy scale such as / 9,j cE E the behavior of 0 ( ) illustrates different tendencies. For instance, 0 ( ) keeps decreasing from = 0.5 to cr= until it vanishes. The values of cr are determined from our calculation (see Fig. 27(a)) as 0.6231, 0.6007, 0.5784, and 0.5634 for energy scales 9, 15, 30, and 50, respectively. The “hump” of the double well potential is not so high in this region and the energy levels are strongly coupled. Such behavior corresponds to two-level crossing. On the other hand, for cr max< where max is giv- en in Table 2, 0 ( ) has an increasing tendency as shown in Fig. 27(a). For max> the “hump” of the double well increases so the energy levels become weakly coupled. Con- sequently, the second harmonic in Eq. (46) becomes domi- nant and leads to a two-level crossing. For large values of anharmonicity parameter (0.65 < ), we obtain results similar to those in [78]. The maximum values of 0( ) peaks at different energy scales are given in Table 2. Table 2. Changing of the maximum of 0( ) peaks EJ/EC max 0 max 9 1.350 0.0045 15 1.125 0.0054 30 0.950 0.0072 50 0.875 0.0090 As also shown in Fig. 27, the peak position of 0 de- pends on the energy scale / .j cE E Besides, the width of the peak grows with decreasing energy scale /j cE E in phase qubit regime. With decreasing / ,j cE E the peak value of 0 ( ) is also suppressed. As shown in the inset of Fig. 27(a), 0 ( ) only reveals tendency for growth when / < 3j cE E for charge qubit regime. Figure 27(b) illus- trates similar results for 1. As can be seen from this fig- ure, 1( ) reveals monotonic decreasing behavior with an increase in the anharmonicity parameter for all / .j cE E The influence of the energy scale /j cE E on splitting of energy state i for fixed value of anharmonicity parame- ter is presented in Fig. 28. This plot clearly illustrates an upward trend of i for / > 50.j cE E The reason for re- stricting /j cE E up to 50 is related to technological achievement in the realization of JJ with a very small ca- pacitances (at a level of femto Farad (fF)) [85]. The energy splitting in ground state 0 increases for energy scale / > 3.j cE E The partial derivative of 0 with respect to energy scale for various is plotted in Fig. 29. As follows from Fig. 28 and Fig. 29, high slope corresponds to the Fig. 28. (Color online) Splitting versus energy scale. Splitting of the ground state (inset shows behavior of 0 for the range 0 Ej/Ec 4) (a). Splitting of the first excited state (inset shows behavior of 1 for the range 0 Ej/Ec 4) (b). Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 333 case of harmonic CPR ( = 0). Increasing up to 2 re- sults in fall of the slope down to zero. As follows from the inset of Fig. 28(a), at small / < 3,j cE E 0 sharply decreases with an increase in / .j cE E Another peculiarity of this region is related to non- sensitivity of results to changing of amplitude of second harmonic . The influence of the energy scale parameter /j cE E on splitting of energy state 1 for fixed value is presented in Fig. 28(b). The splitting of first state 1( / )j cE E reveals behavior similar to the case 0 ( / ).j cE E The inset in Fig. 28(b) shows that at small / < 3,j cE E 1 decreases sharply with an increase in /j cE E similar to 0. Notice that differential plots for the first level also resemble those shown in Fig. 29. 4.2.2. Charge qubits. As mentioned before, the energy scale / < 1j cE E corresponds to the single Cooper box (SCB) charge qubit limit. In this limit, energy spectrum can be described at quasi-charge approach [4,81] similar to quasi-momentum representation in solid-state theory [90] (see also inset Fig. 20(a). Energy gap 0 dependence on anharmonicity parameter presented in Fig. 30(a) resem- bles the phase qubit case in Fig. 27. Similarly to 0 which is the difference between 1 and 0 at = 0.5gn , the “sec- ondary energy gap” 1 is the difference between 2 and 1 at = 1gn . The detailed description can be found in [81]. Notice that i refers to energy gap in charge qubit whereas it refers to splitting of energy states in phase qubit. In Fig. 30(b), the dependence of gap parameters i on energy scale /j cE E is illustrated. This result qualitatively is also in good agreement with Fig. 28. However, in case of SCB the growth of i with /j cE E has revealed a non- linear behavior. The expectation value of number operator n̂ given in Eq. (51) is plotted with respect to gate number gn in Fig. 31 at small bias current = 0.1bi . The n̂ vs gn is experimentally observed for SCB in [91] for junction pa- rameters = 0.215 meVcE and / = 0.16.j cE E As follows from Fig. 31 dependence of n̂ vs gn is not sensitive to . The expectation value of supercurrent ˆ= /s ci I I versus gn is illustrated in Fig. 32 for different an- harmonicity parameters . The positions of the peaks in si vs gn relation is the same as the peaks for = 0 in [81]. Note that the supercurrent is equal to zero when the bias current bi is set to zero. The peaks at half-integer gn val- ues correspond to the tunneling of Cooper pairs from one Fig. 29. (Color online) Differential plot for the splitting parame- ters in the ground state. Fig. 30. (Color online) Results for the charge qubit obtained at ng = 0.5. Fig. 31. (Color online) n versus ng for ib = 0.1. I.N. Askerzade 334 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 electrode to another. When we compare Fig. 32(a) and 32(b), the increasing of bi leads to an increase in the mag- nitude of si while the increasing of anharmonicity parame- ter leads to a decrease in the magnitude of .si It was shown in [54] that the anharmonicity of the CPR is equivalent to the introduction of an effective inductance connected in series to the JJ. The value of effective induct- ance is proportional to the magnitude of the anharmonicity parameter. This implies that such additional inductance leads to an increase in the impedance of the circuit for charge qubit. For that reason, the amplitude of the expecta- tion value of supercurrent si in Fig. 32 is suppressed with increasing . 4.2.3. Silent qubit. The silent qubit is just a low- inductive two-junction interferometer based on JJ with anharmonic CPR and does not require application of half- flux quantum. Such a qubit is called “silent” because of both its high protection against external magnetic field impact and the absence of any state-dependent sponta- neous circular currents. The potential energy of such quantum-mechanical system was described in the papers [66,78,79,80]. As shown in this work and mentionened in section 2, presence of second harmonic in CPR of JJ leads to a two-hump potential ____________________________________________________ 0 1 0 21 2( , ) = cos( ) cos( 2 ) cos( ) cos( 2 ) 2 2 2 2 2 2 c cI I U , (55) _______________________________________________ where 1 2 is difference of the JJ phases, 1 2( )/2, 0= 2 ( / )e are normalized external fluxes. In the absence of external magnetic field one can easily obtain the conditions leading to the double-well en- ergy potential formation (see above). If both junctions (with the same CPR) are of the same size, the energy po- tential remains always symmetric and any state- dependent current is impossible even if an external mag- netic field is applied. However, at different sizes of the junction (different critical currents) the external magnetic field always breaks the potential symmetry and produces a state-dependent current in the loop. In papers [66,77,79,80] influence of external magnetic field on the splitting of energy levels was investigated. It was shown that the ratio /J QE E also has influence on splitting of energy levels. The value of external magnetic field ,e in which splitting parameter remains unchangeable was found. In these papers examples of some logic operations using silent qubit are also considered. 5. Conclusions Results of theoretical and experimental investigations of different JJ with anisotropic and multiband supercon- Fig. 32. (Color online) Expectation value of supercurrent I/Ic . ib =0.05 (a), ib = 0.1 (b). Fig. 33. Energy spectrum of silent qubit. Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 335 ductors show that in the general case CPR has anharmonic character. However, up to present time simple sinusoidal CPR was used to study the dynamics and ultimate perfor- mance of superconducting devices based on JJ. The main subject of this review is the investigation of dynamical properties of JJ with anharmonic CPR. Firstly, numerically calculated I–V characteristics of externally shunted JJ with anharmonic CPR were discussed. We conclude that the second harmonic in the CPR has a strong influence on the I–V curve of the JJ. Inclusion of anharmonicity parameters leads to an increase in the critical current and an enhance- ment of hysteresis in the I–V curves. We confirm that the shunt inductance in the range of 15L also affects the dynamics considerably. Result of calculations of the plasma frequency of JJ with anharmonic CPR as function of anharmonicity pa- rameter was presented. Comparison of calculated plas- ma frequency with experimental data was conducted. Gen- eralizing formulas for both harmonic and sub-harmonic Shapiro steps in the presence of nonzero junction capaci- tance and second harmonic in current-phase relation are discussed. Experimental results related to Shapiro steps in YBCO-based JJ are in good agreement with the theory. Simulations show that consideration of the second harmon- ic in CPR significantly changes the shape and stability properties of fluxon static distribution in long JJ. We conclude that second harmonic in CPR has strong influence on the characteristics of phase qubits based on Josephson junctions, which operate at very low tempera- tures. In contrast to phase qubits, in the limit of charge qubits no considerable effects of anharmonicity are ob- served in the characteristic number of Cooper pair n̂ versus gate number .gn It was observed that the influences of anharmonicity parameter and the bias current bi on the expectation value of supercurrent si in charge qubit are opposite. It was demonstrated that splitting of energy lev- els in phase qubit as well as energy gap in charge qubit reveals similar behavior with energy scale. Characteristics and operations of silent qubit using JJ with anharmonic CPR were also briefly discussed. Finally, we confirm that anharmonic current-phase relation must be taken into ac- count in the experimental realizations of Josephson junc- tion circuits and superconducting qubits. Acknowledgements I thank Professors F.M. Hashimzade, R.R. Guseinov, A. Gencer for the useful discussions, Dr. M. Canturk, Dr. A. Bozbey for collaboration and Dr. Erkan Bostanci for technical help. I am also grateful to the Abdus Salam ICTP for the hospitality during my stay as an associate member. This work was partly supported by the TUBITAK research grant No 111E191. 1. B.D. Josephson, Phys. Lett. 1, 251 (1962). 2. J.M. Rowell, Phys. Rev. Lett. 11, 200 (1963). 3. I.O. Kulik and I.K. Yanson, Josephson Effect in Supe- rconducting Tunneling Structures, John Wiley & Sons, Incorporated (1972). 4. K.K. Likharev, Dynamics of Josephson Junction and Cir- cuits, New York: Gorden Breach Publ. (1986). 5. K.K. Likharev, Physica C 482, 6 (2012). 6. K.K. Likharev, Usp. Phys. Nauk 127, 185 (1979). 7. K.K. Likharev, Rev. Mod. Phys. 51, 101 (1979). 8. A.I. Buzdin, Rev. Mod. Phys. 77, 935 (2005). 9. A.A. Golubov, M.Yu. Kupriyanov, and E. Il’ichev, Rev. Mod. Phys. 76, 411 (2004). 10. C.C. Tsuei and J.R. Kirtley, Rev. Mod. Phys. 72, 969 (2000). 11. J.R. Kirtley, Rep. Prog. Phys. 73, 126501 (2010). 12. M. Sigrist and T.M. Rice, Rev. Mod. Phys. 67, 503 (1995). 13. Yu.A. Kolesnichenko, A.N. Omelyanchouk, A.M. Zagoskin, Fiz. Nizk. Temp. 30, 714 (2004) [Low Temp. Phys. 30, 535 (2004)]. 14. A. Barone and G. Paterno, Physics and Application of the Josephson Effect, Wiley-InterScience Publications, Canada (1982). 15. I. Askerzade, Unconventional Superconductors: Anisotropy and Multiband Effects, Springer (2012). 16. M. Sigrist and T.M. Rice, J. Phys. Soc. Jpn. 61, 4283 (1992). 17. Y. Tanaka, Phys. Rev. Lett. 72, 3871 (1994). 18. Y. Tanaka and S. Kashiwaya, Phys. Rev. B 56, 897 (1997). 19. A.F. Andreev, Sov. Phys. JETP 19, 1228 (1964). 20. L.N. Bulaevskii, V.V. Kuzii, and A.A. Sobyanin, JETP Lett. 25, 290 (1977). 21. N.N. Bogolyubov, V.V. Tolmachev, and D.V. Shirkov, New Method in Theory of Superconductivity, Nauka, Moscow (1958). 22. V. Ambreokar and A. Baratoff, Phys. Rev. Lett. 10, 486 (1963). 23. I.O. Kulik and A.N. Omel’yanchuk, JETP Lett. 21, 96 (1975). 24. I.O. Kulik and A.N. Omel’yanchuk, Fiz. Nizk. Temp. 4, 296 (1978) [Sov. J. Low Temp. Phys. 4, 142 (1978)]. 25. J. Nagamatsu, N. Nakagawa, T. Muranaka, Y. Zenitani, and J. Akimitsu, Nature, 410, 63 (2001). 26. Y. Izyumov and E. Kurmaev, High-Tc Superconductors Based on FeAs Compounds, Springer (2010). 27. Y. Erin and A.N. Omelyanchouk, Fiz. Nizk. Temp. 36, 1204 (2010) [Low Temp. Phys. 36, 969 (2010)]. 28. A.I. Buzdin, JETP Lett. 78, 583 (2003). 29. A.I. Buzdin and M.Yu. Kupriyanov, JETP Lett. 53, 321 (1991). 30. A.A. Golubov, M.Yu. Kupriyanov, and Ya.V. Fominov, JETP Lett. 75, 190 (2002). 31. Y. Bazaliy, E. Demler, and S.-C. Zhang, Phys. Rev. Lett. 80, 2917 (1998). 32. F.S. Bergeret, A.F. Volkov, and K.B. Efetov, Rev. Mod. Phys. 77, 1321 (2006). I.N. Askerzade 336 Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 33. I.A. Garifullin, D.A. Tikhonov, N.N. Garif’yanov, L. Lazar, Yu.V. Goryunov, S.Ya. Khlebnikov, L.R. Tagirov, K. We- sterholt, and H. Zabel, Phys. Rev. B 66, R020505 (2002). 34. P. Komissinskiy, G.A. Ovsyannikov, I.V. Borisenko, Yu.V. Kislinskii, K.Y. Constantinian, A.V. Zaitsev, and D. Winkler, Phys. Rev. Lett. 99, 017004 (2007). 35. L.R. Gor’kov and V.Z. Kresin, Physica C 367,103 (2002). 36. A.J. Dahm, A. Denenstein, T.F. Finnegan, D.N. Langenberg, and D.J. Scalapino, Phys. Rev. Lett. 20, 859 (1968). 37. N. Grønbech-Jensen, M.G. Castellano, F. Chiarello, M. Ci- rillo, C. Cosmelli, L.V. Filippenko, R. Russo, and G. Torrioli, Phys. Rev. Lett. 93, 107002 (2004). 38. E. Il’ichev, M. Grajcar, R. Hlubina, R.P.J. IJsselsteijn, H.E. Hoenig, H.-G. Meyer, A. Golubov, M.H.S. Amin, A.M. Zagoskin, A.N. Omelyanchouk, and M.Yu. Kupriyanov, Phys. Rev. Lett. 86, 5369 (2001). 39. E. Il’ichev, V. Zakosarenko, L. Fritzsch, R. Stolz, H.E. Hoenig, H.-G. Meyer, M. Gotz, A.B. Zorin, V.V. Khanin, A.B. Pavolotsky, and J. Niemeyer, Rev. Sci. Instrum. 72, 1882 (2001). 40. A.H. Silver and J.E. Zimmerman, Phys. Rev. 157, 317 (1967). 41. R. Rifkin and B.S. Deaver, Phys. Rev. B 13, 3894 (1976). 42. E. Il'ichev, H.E. Hoenig, H.-G. Meyer, A.B. Zorin, V.V. Khanin, M. Götz, A.B. Pavolotsky, and J. Niemeyer, Physica C 352, 141 (2001). 43. E. Il’ichev, V. Zakosarenko, R.P.J. IJsselsteijn, H.E. Hoenig, H.-G. Meyer, M.V. Fistul, and P. Müller, Phys. Rev. B 59, 11502 (1999). 44. T. Bauch, F. Lombardi, F. Tafuri, A. Barone, G. Rotoli, P. Delsing, and T. Claeson, Phys. Rev. Lett. 94, 087003 (2005). 45. G.A. Ovsyannikov and K.I. Konstantinyan, Fiz. Nizk. Temp. 38, 423 (2012) [Low Temp. Phys. 38, 333 (2012)]. 46. C. Chialvo et al., cond-mart, arxiv1005.2630. 47. Annica M. Black-Schaffer and Jacob Linder, Phys. Rev. B 82, 184522 (2010). 48. L. Fu, C.L. Kane, and E.J. Mele, Phys. Rev. Lett. 98, 106803 (2007). 49. M.Z. Hasan and C.L. Kane, Rev. Mod. Phys. 82, 3045 (2010). 50. Xiao-Liang Qi and Shou-Cheng Zhang, Rev. Mod. Phys. 83, 1057 (2011). 51. L. Fu and C.L. Kane, Phys. Rev. B 79,161408 (2009). 52. P.A. Ioselevich and M.V. Feigel’man, Phys. Rev. Lett. 106, 077003 (2011). 53. J.R. Williams, A.J. Bestwick, P. Gallagher, Seung Sae Hong, Y. Cui, Andrew S. Bleich, J.G. Analytis, I.R. Fisher, and D. Goldhaber–Gordon, Phys. Rev. Lett. 109, 056803 (2012). 54. A. Zubkov, M. Kupriyanov, and V. Semenov, Fiz. Nizk. Temp. 7, 1365 (1981) [Sov. J. Low Temp. Phys. 7, 661 (1981)]. 55. C.B. Whan and C.J. Lobb, J. Appl. Phys. 77, 382 (1995). 56. A.B. Cawthorne, C.B. Whan, and C.J. Lobb, J. Appl. Phys. 84, 1126 (1998). 57. M. Canturk and I.N. Askerzade, IEEE Appl. Supercond. 22, 1400106 (2012). 58. E. Goldobin, D. Koelle, R. Kleiner, and A. Buzdin, Phys. Rev. B 76, 224523 (2007). 59. N. Calander, T. Claeson, and S. Rudner, Appl. Phys. Lett. 39, 504 (1981). 60. I.N. Askerzade and V.K. Kornev, Radiotekh. Elekt. 39, 869 (1994). 61. I.N. Askerzade, Techn. Phys. 48, 1496 (2003). 62. M. Abramovitz and A. Stegun, Handbook on Math. Functions, Dover, New York (1972). 63. I.N. Askerzade, Techn. Phys. Lett. 31, 622 (2005). 64. S. Shapiro, Phys. Rev. Lett. 11, 80 (1963). 65. D. Cassel, G. Pickartz, M. Siegel, E. Goldobin, H.H. Kohl- stedt, A. Brinkman, A.A. Golubov, M.Yu. Kupriyanov, and H. Rogalla, Physica C 450, 76 (2001). 66. V.K. Kornev, T.Y. Karminskaya, Y.V. Kislinskii, P.V. Ko- missinki, K.Y. Constantinian, and G.A. Ovsyannikov, Physica C 435, 27 (2006). 67. P.V. Komissinski, K.I. Constantinian, Yu. Kislinskii, and G.A. Ovsyannikov, Fiz. Nizk. Temp. 30, 795 (2004) [Low Temp. Phys. 30, 599 (2004)]. 68. Y. Kislinskii, P. Komissinski, K. Constantinian, G. Ovsyan- nikov, T. Karminskaya, I. Soloviev, and V. Kornev, JETP 101, 494 (2005). 69. R. Kleiner, A.S. Katz, A.G. Sun, R. Summer, D.A. Gajewski, S.H. Han, S.I. Woods, E. Dantsker, B. Chen, K. Char, M.B. Maple, R.C. Dynes, and John Clarke, Phys. Rev. Lett. 76, 2161 (1996). 70. P.Kh. Atanasova, T.L. Boyadjiev, Yu.M. Shukrinov, and E.V. Zemlyanaya, Proc. FDM10, Lozenetz, Bulgaria (2010). 71. P.Kh. Atanasova, T.L. Boyadjiev, Yu.M. Shukrinov, and E.V. Zemlyanaya, J. Phys., Conf. Ser. 248, 012044 (2010). 72. P.Kh. Atanasova, T.L. Boyadjiev, Yu.M. Shukrinov, and E.V. Zemlyanaya, Lecture Notes Computer Science 6046, 347 (2011). 73. Y.S. Galperin and A.T. Filippov, Sov. Phys. JETP 59, 89 (1984). 74. M.A. Nielsen and I.L. Chuang, Quantum Computation and Quantum Information, Cambridge, University Press (2000). 75. K.A. Valiev, Phys. Usp. 48, 1 (2008). 76. T. Bauch, T. Lindstro, F. Tafuri, G. Rotoli, P. Delsing, T. Claeson, and F. Lombardi, Science 311, 57 (2006). 77. M.H.S. Amin, A.Yu. Smirnov, A.M. Zagoskin, T. Lind- ström, S.A. Charlebois, T. Claeson, and A.Ya. Tzalenchuk, Phys. Rev. B 71, 064516 (2005). 78. N. Klenov, V. Kornev, and N. Pedersen, Physica C 435, 114 (2006). 79. N. Klenov, V. Kornev, A. Vedyayev, N. Ryzhanova, N. Pu- gach, T. Rumyantseva, J. Phys., Conf. Ser. 97, 012037 (2008). 80. N. Klenov, N. Pugach, A. Sharafiev, S. Bakursky, and V. Kornev, Phys. Solid State 52, 2246 (2010). 81. M. Canturk, E. Kurt, and I.N. Askerzade, Int. J. Comput. Math. Elect. Electron. Eng. 30, 775 (2011). 82. M. Canturk and I.N. Askerzade, IEEE Appl. Supercond. 23, 3541 (2011). Effects of anharmonicity of current-phase relation in Josephson junctions Low Temperature Physics/Fizika Nizkikh Temperatur, 2015, v. 41, No. 4 337 83. G. Wendin and V.S. Shumeiko, Fiz. Nizk. Temp. 33, 957 (2007) [Low Temp.Phys. 33, 724 (2007)]. 84. T. Yamashita, K. Tanikawa, S. Takahashi, and S. Maekawa, Phys. Rev. Lett. 95, 097001 (2005). 85. N. Nakamura, Y.A. Pashkin, and J.S. Tsai, Nature 398, No. 6730, 786 (1999). 86. K.K. Likharev and A. Zorin, J. Low Temp. Phys. 59, 347 (1985). 87. A. Bjorek and G. Golub, SIAM Rev. 19, 5 (1977). 88. D. Evans and S. Okolie, Comput. Math. Appl. 8, 175 (1982). 89. I.N. Askerzade, Tech. Phys. 56, 744 (2011). 90. J. Zaiman, Principles of the Solids, Cambridge Univ. Press, UK (1995). 91. V. Bouchiat, D. Vion, P. Joyez, D. Esteve, C. Urbina, and M.H. Devoret, Appl. Supercond. 6, 491 (1998).