Valence fluctuations in Sn(Pb)₂P₂S₆ ferroelectrics

The valence fluctuations which are related to the charge disproportionation of phosphorous ions P⁴⁺+P⁴⁺→P³⁺+P⁺⁵ are the origin of ferroelectric and quantum paraelectric states in Sn(Pb)₂P₂S₆ semiconductors. They involve recharging of SnPS ₃ or PbPS ₃ structural groups which can be represented as hal...

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Bibliographic Details
Date:2016
Main Authors: Yevych, R., Haborets, V., Medulych, M., Molnar, A., Kohutych, A., Dziaugys, A., Banys, Ju., Vysochanskii, Yu.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2016
Series:Физика низких температур
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/129343
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Valence fluctuations in Sn(Pb)₂P₂S₆ ferroelectrics / R. Yevych, V. Haborets, M. Medulych, A. Molnar, A. Kohutych, A. Dziaugys, Ju. Banys, Yu. Vysochanskii // Физика низких температур. — 2016. — Т. 42, № 12. — С. 1477-1486. — Бібліогр.: 39 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine