Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts
Untreated wastewater discharges may have significant short term and long term effects on the quality of a river system. Present study was undertaken to assess the present status of the water quality of River Kabul near Peshawar in Pakistan. Seven sites were sampled upstream and downstream in River K...
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Інститут колоїдної хімії та хімії води ім. А.В. Думанського НАН України
2013
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Цитувати: | Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts / Ullah Zahid, Khan Hizbullah, Waseem Amir, Mahmood Qaisar, Farooq Umar // Химия и технология воды. — 2013. — Т. 35, № 4. — С. 307-319. — Бібліогр.: 30 назв. — англ. |
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irk-123456789-1307782018-02-22T03:03:00Z Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts Ullah Zahid Khan Hizbullah Waseem Amir Mahmood Qaisar Farooq Umar Технология водоподготовки и деминерализация вод Untreated wastewater discharges may have significant short term and long term effects on the quality of a river system. Present study was undertaken to assess the present status of the water quality of River Kabul near Peshawar in Pakistan. Seven sites were sampled upstream and downstream in River Kabul in 2009. Samples were also taken from waste water channel (Budni Drain) that carries wastewater of Peshawar Industrial Estate as well as the domestic sewers to assess the pollution contribution of these sources to River Kabul. Physico-chemical and microbiological parameters of the samples were analyzed during the study, as well as possible sources of contamination were investigated. The study showed that the pollution level in river is rising from upstream (at city entrance) to downstream (at city exit) due to discharge of domestic waste water effluents, agricultural activities, and solid waste dumping directly into the river. 2013 Article Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts / Ullah Zahid, Khan Hizbullah, Waseem Amir, Mahmood Qaisar, Farooq Umar // Химия и технология воды. — 2013. — Т. 35, № 4. — С. 307-319. — Бібліогр.: 30 назв. — англ. 0204-3556 http://dspace.nbuv.gov.ua/handle/123456789/130778 en Химия и технология воды Інститут колоїдної хімії та хімії води ім. А.В. Думанського НАН України |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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Технология водоподготовки и деминерализация вод Технология водоподготовки и деминерализация вод |
spellingShingle |
Технология водоподготовки и деминерализация вод Технология водоподготовки и деминерализация вод Ullah Zahid Khan Hizbullah Waseem Amir Mahmood Qaisar Farooq Umar Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts Химия и технология воды |
description |
Untreated wastewater discharges may have significant short term and long term effects on the quality of a river system. Present study was undertaken to assess the present status of the water quality of River Kabul near Peshawar in Pakistan. Seven sites were sampled upstream and downstream in River Kabul in 2009. Samples were also taken from waste water channel (Budni Drain) that carries wastewater of Peshawar Industrial Estate as well as the domestic sewers to assess the pollution contribution of these sources to River Kabul. Physico-chemical and microbiological parameters of the samples were analyzed during the study, as well as possible sources of contamination were investigated. The study showed that the pollution level in river is rising from upstream (at city entrance) to downstream (at city exit) due to discharge of domestic waste water effluents, agricultural activities, and solid waste dumping directly into the river. |
format |
Article |
author |
Ullah Zahid Khan Hizbullah Waseem Amir Mahmood Qaisar Farooq Umar |
author_facet |
Ullah Zahid Khan Hizbullah Waseem Amir Mahmood Qaisar Farooq Umar |
author_sort |
Ullah Zahid |
title |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts |
title_short |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts |
title_full |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts |
title_fullStr |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts |
title_full_unstemmed |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts |
title_sort |
water quality assessment of river kabul at peshawar, pakistan: industrial and urban wastewater impacts |
publisher |
Інститут колоїдної хімії та хімії води ім. А.В. Думанського НАН України |
publishDate |
2013 |
topic_facet |
Технология водоподготовки и деминерализация вод |
url |
http://dspace.nbuv.gov.ua/handle/123456789/130778 |
citation_txt |
Water quality assessment of River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts / Ullah Zahid, Khan Hizbullah, Waseem Amir, Mahmood Qaisar, Farooq Umar // Химия и технология воды. — 2013. — Т. 35, № 4. — С. 307-319. — Бібліогр.: 30 назв. — англ. |
series |
Химия и технология воды |
work_keys_str_mv |
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first_indexed |
2025-07-09T14:13:21Z |
last_indexed |
2025-07-09T14:13:21Z |
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fulltext |
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4 307
Zahid Ullah1,2, Hizbullah Khan2, Amir Waseem3,
Qaisar Mahmood3, Umar Farooq3
WAter QUAlity AssessMent oF river KAbUl At
PesHAWAr, PAKistAn: indUstriAl And UrbAn
WAsteWAter iMPActs
1 Allama Iqbal Open University, Islamabad;
2 University of Peshawar, Peshawar;
3 COMSATS Institute of Information Technology, Abbottabad, Pakistan
Untreated wastewater discharges may have significant short term and long term
effects on the quality of a river system. Present study was undertaken to assess the
present status of the water quality of River Kabul near Peshawar in Pakistan. Seven
sites were sampled upstream and downstream in River Kabul in 2009. Samples
were also taken from waste water channel (Budni Drain) that carries wastewater
of Peshawar Industrial Estate as well as the domestic sewers to assess the pollution
contribution of these sources to River Kabul. Physico-chemical and microbiological
parameters of the samples were analyzed during the study, as well as possible sources
of contamination were investigated. The study showed that the pollution level in
river is rising from upstream (at city entrance) to downstream (at city exit) due to
discharge of domestic waste water effluents, agricultural activities, and solid waste
dumping directly into the river.
Keywords: River Kabul (Pakistan), water quality, industrial waste water, physico-
chemical, microbial parameters, heavy metals.
introduction
Water quality characteristics of aquatic environment arise from a multi-
tude of physical, chemical and biological interactions. A regular monitoring
of water bodies with required number of parameters in relation to water qual-
ity not only prevents the outbreak of diseases but also help to mitigate occur-
rence of hazards [1]. Rivers are vital and vulnerable freshwater systems that
are critical for the sustainability of all life. However, the declining quality of
the waters in these systems threatens their sustainability. Rivers are waterways
of strategic importance across the world, providing main water resources for
domestic, industrial, and agricultural purposes [2]. Discharge of pollutants to a
© Zahid Ullah, Hizbullah Khan, Amir Waseem, Qaisar Mahmood, Umar Farooq, 2013
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4308
water resource system from domestic sewers, storm water discharges, industrial
wastes discharges, agricultural runoff and other sources, all of which may be
untreated, can have both short term and long term significant effects on the
quality of a river system [3]. It is a common practice for people living along the
river catchments to discharge their domestic waste as well as human excreta
into rivers [2, 4].
Rivers included in most recent studies are the Huluka and Alaltu Rivers of
Ambo, Ethiopia [5], Juru River, Malaysia [6], Owo River, Lagos-Nigeria [7],
Neponset Watershed, Massachusetts, US [8], Sabarmati River at Ahmedabad,
India [9], Guksu River, Turkey [10], River Mahi, India [11]. Nansha River,
Beijing Central Region China [12], Jiulong River, China [13], River Tame, Bir-
mingham, UK [14], Weihe River, China [15], Chenab River, Pakistan [16].
Water quality of few rivers like Siran river [17], Chenab [18], Indus at Kotri
[19], Neelam [20] and Lei [21] have been reported in Pakistan. Studies on the
water quality of River Kabul of NWFP [22] under High River flow and Kabul
at Noshera [23] has been conducted more than a decade ago. Results from
these studies revealed that anthropogenic activities greatly deteriorated water
quality in the downstream sections of the major rivers as a result of cumulative
effects from upstream development and in small tributaries with inadequate
wastewater treatment facilities.
The study area starts from Warsak dam up to 50 km downstream (Khyber
Pakhtunkhawa Pakistan). The river receives wastewater from domestic sew-
ers, storm water discharges, industrial wastes discharges and agricultural run-
off covering an area of 1257 km2 with a population of more than 3.6 million.
Peshawar Industrial Estate (Hayatabad) is located on the Peshawar Jamrood
Kabul Highway in the North West of Peshawar. According to Sarhad Develop-
ment Authority, the "Hayatabad Industrial Estate" (HIE) housed 272 opera-
tional units. HIE spread over an area of 884 acres, can be divided into six main
domains namely, Match, vegetable ghee/oil, pharmaceutical, marble, chemi-
cals and woolen mills.
The quality of river was studied more than a decade ago in relation to
industrial eff luent load at Noshera which is 61 km downstream to Kabul
at Warsak (Peshawar) [22]. With the rapid expansion of industrialization
and population growth caused concerns over the water quality of the River
Kabul. The whole region relies on the water supplied by the Kabul for its
agriculture, domestic and industrial activities. Untreated wastewater dis-
charges into freshwater bodies like River Kabul may affect the aquatic biota
as well as dependent human communities indirectly. It is therefore impera-
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4 309
tive to assess the status of water quality of river and industrial waste water
pollution.
study area and monitoring sites. The study area is located in the Pesha-
war Division (Khyber Pakhtunkhawa Pakistan), starting from Warsak dam up
to 50 km downstream to River Kabul. Sampling from industrial wastewater
at (Budni Drain) before joining to Shah Alam River (one of the River Kabul
branch after splitting into three) was also carried out. Other seven sampling
stations were selected on main River Kabul and its three main branches after
splitting, after joining branches and after the joining of Swat River to main
River Kabul (Fig. 1).
Fig. 1. Map of River Kabul showing sampling sites.
Water sampling and chemical analysis. Water samples were collected twice
in winter spell (December, January) and summer spell (June, July) in 2009
from the allocated sampling sites (see Fig. 1). Water samples (1500 ml each)
were collected manually at each site using acid-washed (10%, v/v HCl) into
HDPE bottles. The pre-washed bottles were rinsed thrice with water samples
on the site before sample collection.
Water samples were stored in a cooler box and transported to the laboratory.
Chemical oxygen demand (COD) concentration was determined by analyzing
the oxygen demand by using colorimetric method (Lovibond, Dortmund, Ger-
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4310
many) [24]. Total suspended solids (TSS), Alkalinity (A
T
), Cations and Anions,
E. coli were determined using Standard methods for water and wastewater treat-
ment [24]. The pH, dissolved oxygen (DO), electrical conductivity (EC), total
dissolved solids (TDS) and temperature were measured on-site using DO/EC
meter (Hanna, USA). Turbidity (Nephlometric turbidity unit; NTU) measure-
ment was made by using turbidity meter (Lovibond, Dortmund, Germany). Sam-
pling was always done in clear weather condition to prevent any abrupt changes
in measurements, and to avoid unsteady conditions; sampling was not conducted
after rainfall events. Sampling and measurements along each individual site were
done continuously from upstream to downstream.
results and discussion
The values of various physicochemical parameters at different sampling
sites (S-1–S-8), and their average of all sampling sites along with the National
Environmental Quality Standards (NEQS), National Standards for Drink-
ing Water Quality Pakistan (NSDWQ-Pak), US and EU values for surface
waters have been given in Table [25]. The rapid urbanization and industrial
development has created severe pollution loads in inland surface water bodies
in urban localities. Chemical quality assessment of such surface bodies may
widely reect the pollution load and anthropogenic pressure on surface water
systems. Water entering a river environment is derived mainly from three
important sources; surface run-off, through flow and interflow and base flow
or ground water flow [26]. All these sources have a direct influence on the net
chemical composition of river waters. River water is generally a dilute aque-
ous solution whose chemical qualities are acquired from atmospheric, soil,
and rock sources, the relative contributions of which is a function of climate
modified by human activities both directly by effluent discharges and indi-
rectly by agricultural activities, land-use/land-cover changes and pollutant
discharges [27].
The surface water pollution issue has been enlisted as one of the most seri-
ous problems in developing countries. Most of the rivers in the urban areas of
the developing world are the end point of effluents discharged from the indus-
tries. In Pakistan, urban runoff and sewerage disposal in river catchments areas
is the major problem of river water quality maintenance. The wastewater from
urban runoff and industrial discharges contributes to water resources degrada-
tions, reduces agriculture production and affects public health.
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4 311
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ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4312
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ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4 313
The analysis results of study sites were given in Fig. 2 – 4. The pH is the
indicator of acidic and alkaline condition of water status. NEQS suggest 6.5 –
8.5 range of pH for water for any purposes in that respect; the mean value indi-
cated moderately alkaline water of river. The pH varied from 7.4 to 7.6 in vari-
ous sampling sites, with maximum of 7.7 of site S-1, which is the pH of Budni
nullah, which joins to Shah Alam branch of River Kabul (see Fig. 1). Higher
pH could be attributed to bicarbonates and carbonate of calcium and magne-
sium in water which may be due to the geology of the region in which limestone
is the most common.
900
700
500
300
100
S-2 S-3 S-4 S-5 S-6 S-7 S-8
Sampling sites
Turbidity (NTU)
TDS (mg/L)
COD (mg/L) EC (µs/cm)
Alkalinity (mg/L)
U
ni
ts
(N
TU
, m
g/
L
&
µ
S/
cm
)
Fig. 2. Variation of Turbidity, COD, EC, TDS and Alkalinity of River Kabul for
various sampling sites.
DO may be a potential indicator of river quality in assessing urban impacts
on river ecosystem. DO of River Kabul ranged between 3.0 mg/L to 7.5 mg/L
with mean of 5.6 mg/L. The maximum mean DO was found at S-8 (7.5), fol-
lowed by S-6 (7.3) both points are the entry and exit of the river to region (see
Fig. 1). This further indicated the turbulences and owrate of river water at dif-
ferent sites, which may be benecial for dissolved solid breakdown through self-
pollution regulating mechanisms of fresh water system. A sharp decreasing
trend was observed down stream at S-3, where Budni Drain meets upstream
fresh water. The water quality in terms of DO content is always of primary
importance because at the waste discharge points in river, the DO is required
for aerobic oxidation of the wastes. Also, DO levels are important in the natural
self-purication capacity of the river. A good level of DO in sampling sites of the
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4314
river indicated a high re-aeration rate and rapid aerobic oxidation of biological
substances. The difference among sampling sites for DO was of least signi-
cance in upstreams and probably it might be related directly to the turbulences
and owrate of water in the river system, however in down streams (Shah Alam
branch) lower DO values indicate the level of pollution due to anthropogenic
activities.
COD is also an important parameter of water indicating the health sce-
nario of freshwater bodies. COD is often used as a measurement of organic
pollutants in natural and waste waters and to assess the strength of waste such
as sewage and industrial effluent waters. COD varied from 75–282 mg/L with
mean of 116 mg/L of the river (see Fig. 2). A trend of increasing COD level was
observed at downstream sites (S-3 and S-7); however, it diluted to lower value at
S-8 downstream, where Swat River joins the Kabul River. Higher COD at S-3
shows the pollution load caused by the mixing of sewage water, garbage dump-
ing and industrial effluents without any pretreatment.
Conductivity of river water was not signicantly different among sampling
sites except upstream at S-6 which is possibly dilution due to huge water res-
ervoir of Warsak Dam. The values varying from 320 to 821 µs/cm with mean
of 609 µs/cm (see Fig. 2). High conductivity at sites S-3 indicates the mixing
of the industrial and sewerage waste in river water as this site is located down-
stream to S-1 whose conductivity was found to be 1151 µs/cm.
There is no significant variation observed in turbidity of River Kabul for
different sampling sites (see Fig. 2). Turbidity varied from 18 to 99 NTU with
mean of 45 NTU. It was higher possibly due to the mixing of domestic sewer-
age water and industrial efuents in river (at S-3). The increasing turbidity at
downstream sites was due to the ow turbulences (at S-7) and further decreasing
due to settling factors.
TDS and A
T
further indicate the salinity and alkalinity behavior of river
water. TDS and A
T
content of river water was in the range of 350 – 830 mg/L
and 115 – 195 mg/L with mean of 578 to 140 mg/L respectively. The maximum
TDS and A
T
was observed at S-3 sampling site indicating the mixing of pol-
lutants in river from anthropogenic activities by well populated city such as the
mixing of sewerage, clothes washing and garbage dumping, which are some
common activities at the riverbank in this area. The overall increasing order of
TDS was observed from upstream to downstream of the river (see Fig. 2). Higher
TDS in water system increases the chemical and biological oxygen demand and
ultimately depletes the dissolved oxygen level in water.
Anion concentrations of Cl–, NO3–, and SO
4
2– values are given in Fig. 3.
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4 315
250
150
50
S-2 S-3 S-4 S-5 S-6 S-7 S-8
Sampling sites
Nitrate Sulfate Chloride
mg/L
Fig. 3. Variation of anions of River Kabul for various sampling sites.
The values of these ions in River Kabul water is not exceeding the guide-
line values of NSDWQ and EU drinking water standards, however the chlo-
ride contents in water is higher than the US irrigation water guideline value
(see Table). The detection of higher concentration of chloride in freshwa-
ter suggests the presence of pollutants. Nevertheless, chloride concentration
at different sampling site did not exhibit a clear trend with respect to point
or non-point pollution sites. Anions content of Cl–, NO3–, and SO
4
2– varied
from 120 – 270, 8 – 13.2 and 70 – 180 mg/L with mean of 196.5 mg/L, 10.3
and 126 mg/L respectively (see Fig. 4). An ion concentration values in S-1
exceeds the limit of USA wastewater effluent, however under the acceptable
values of NEQS-Pak.
Heavy metals are known to have serious health implications including car-
cinogenesis induced tumor promotion [28]. The growing consciousness about
the health risks associated with environmental chemicals has brought a major
shift in global concern towards prevention of heavy metal accumulation in soil,
water and vegetables. Atmospherically driven heavy metals have been shown to
significantly contaminate soil and vegetables causing a serious risk to human
health when plant based foodstuffs are consumed [29]. Dietary intake of trace
elements depends also on irrigational water use. There may not always be a
strong relationship between the concentrations of trace elements in soil and
plants, but there always exists a strong relationship between their concentra-
tions in irrigational water and plants [30].
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0.2
0.6
1.0
1.2
S-2 S-3 S-4 S-5 S-6 S-7 S-8
Sampling sites
Cr Cu Fe Ni Cd Pb
mg/L
Fig. 4. Variation of heavy metals of River Kabul for various sampling sites.
Thus, the deposition of heavy metals in water bodies can doubly increase
the human intake through food chain as well as through drinking water. Most
of the surface discharge sources contaminate soil and water bodies especially
the industrial waste water without pretreatment which carries large amount of
heavy metal.
The concentration values of Fe [Fe(II)+Fe(III)], Ni(II), Pb(II) was found
to be higher than the NSDWQ and EU drinking water guidelines (see Table),
where as Cr [Cr(III)+Cr(VI], Cu(II) and Cd(II) are present under the stan-
dard limits. The values of Fe, Ni, Pb varies from 0.5 – 1.4, 0.01 – 0.2, and
0.01 – 0.5 mg/L respectively (see Fig. 4). Most of the heavy metal pollution is
caused by the mixing of Industrial wastewater; however geology of the regions
is also contributing in this load.
The coli-form bacteria count (E. coli) in the river water is also alarmingly
high and is a potential threat to humans’ population in vicinity of the river
which uses its water. Fig. 5 shows that up stream sampling site of S-6 are less
polluted with an average of 650 CFU/100 mL. The most polluted site was found
to be the S-3 due to S-1 waste water mixing downstream. Kabul River also
shows the bacterial pollution, even after joining of Swat River downstream at
S-8 which also shows the level of bacterial pollution in Swat River. The E. coli
values of river varied from 551 – 5230 with mean of 1740 CFU/100 mL.
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1000
3000
5000
S-2 S-3 S-4 S-5 S-6 S-7 S-8
Sampling sites
E.
C
ol
i (
C
FU
/1
00
m
L)
Fig. 5. Variation of E. Coli of River Kabul for various sampling sites.
Upon the comparison of NSDWQ, EU and US standards that no colonies
should be found in 100 ml of sample (see Fig. 5). Variation of E. coli of River
Kabul for various sampling sites. This contamination is caused by discharge
of domestic waste water directly into the river without any treatment, open
defecation by people, runoff from agricultural land into river as animal
manure is used in the fields as fertilizers.
conclusions
The water quality of the River Kabul is deteriorating due to several fac-
tors; most noteworthy is the anthropogenic activities like, agriculture, indus-
try, domestic use of water and discharge in to the river without any pretreat-
ment. Most of the parametric values show increasing trend during last decade.
Increased anion concentration, high EC, COD, E. coli and low DO over the
period of time suggesting that the agriculture water runoff, industrial and
domestic wastewater was being mixing in River Kabul. The following recom-
mendations have been proposed.
– To increase the availability and conservation of water, the water used in
industries of HIE for cooling and other purposes may be reused.
– Recycling of waste and bi-product recovery practices should be encour-
aged to save the resources.
– Pollution control measures may be immediately adopted in HIE Pesha-
war e.g. wastewater treatment facilities may be installed in the industrial area,
other than the old outdated previously installed. Each industry should have
ISSN 0204–3556. Химия и технология воды, 2013, т.35, №4318
primary treatment including screening, sedimentation and neutralization on
the premises of the factory to decrease the load of suspended materials and
minimize the extent of pollution load and reduce biological oxygen demand,
prior to their discharge into the receiving water bodies.
– Agricultural runoff, use of pesticides and fertilizer should be controlled
through awareness and education in the down stream project area.
– In HIE industries may be categorized in term of wastewater disposal.
The wastewater of these industries may be collected and treated/disposed at
one place to help in abatement of pollution. For example marble factories waste
water/effluents could be collected at one place and separate treatment could be
caries out.
– Integrated approach for effective solid waste management needs to
be adopted to stop pollutants entrance into surface and ground water sources
present in the project area. It should be obligation of all the relevant agencies to
regularly test the industrial effluents either through their own or other certified
well-known laboratories of repute in the country.
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Received 14.12.2011
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