A simple manifold flow injection analysis for determining phosphorus in presence of arsenate
A simple manifold flow injection analysis (FIA) for determining phosphorus in presence of arsenate in water, by the on-line reduction of As(V) to As(III) using sodium sulphite. The FIA method is applicable for the determination of phosphorus in water samples containing less than 0.37μg mL⁻¹ of AsO₄...
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| Datum: | 2014 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | English |
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Інститут колоїдної хімії та хімії води ім. А.В. Думанського НАН України
2014
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| Schriftenreihe: | Химия и технология воды |
| Schlagworte: | |
| Online Zugang: | http://dspace.nbuv.gov.ua/handle/123456789/130846 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | A simple manifold flow injection analysis for determining phosphorus in presence of arsenate / V. Gerez, K. Rondano, C.E.L. Pasquali // Химия и технология воды.— 2014.— Т. 36 № 1.— С. 38-46.— Бібліогр.: 23 назв.— англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Zusammenfassung: | A simple manifold flow injection analysis (FIA) for determining phosphorus in presence of arsenate in water, by the on-line reduction of As(V) to As(III) using sodium sulphite. The FIA method is applicable for the determination of phosphorus in water samples containing less than 0.37μg mL⁻¹ of AsO₄³⁻ A solution obtained by mixing 6.30g of Na₂SO₃ (1M), 5.0 ml H₂SO₄ 18 M completed up to 50 ml with deionized distilled water was used to reduce on line As(V) to As(III), using a reactor of 0.30m. The limit of detection is 0.05584 ± 0.00167μg mL⁻¹ P— P0₄³⁻ and sampling frequency is 45 samples per hour. It is a simple and low cost methodology, easily applicable in the determination of phosphorus in samples of water contaminated with arsenate. |
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