Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics

Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of Zn...

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Дата:2006
Автори: Jong-Chul Lee, Joon-Hyung Lee, Jeong-Joo Kim, Golub, V., Sang-Hee Cho, O`Connor, C.J., Caruntu, D., Cushing, B.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2006
Назва видання:Functional Materials
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/134187
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ.

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spelling irk-123456789-1341872018-06-13T03:04:18Z Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics Jong-Chul Lee Joon-Hyung Lee Jeong-Joo Kim Golub, V. Sang-Hee Cho O`Connor, C.J. Caruntu, D. Cushing, B. Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of ZnFe₂O₄, however, ZnO and Fe₂O₃ were produced first when the metal citric acids were decomposed at low temperature. A single phase of ZnFe₂O₄ was subsequently obtained when a heat treatment was conducted at 500°C for 2 h. On the other hand, in order to examine the effect of particle size on magnetic characteristics of Ni-Zn ferrites, nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders with particle sizes of approximately 7, 25 and 100 nm were prepared by coprecipitation and citrate precursor methods. The magnetic characteristics of the ultrafine (7 nm) and coarse (100 nm) nanocrystalline ferrites showed differences. These differences are attributed to cation disordering at the surfaces of particles, wich becomes increasingly dominant as the particle size decreases. 2006 Article Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/134187 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of ZnFe₂O₄, however, ZnO and Fe₂O₃ were produced first when the metal citric acids were decomposed at low temperature. A single phase of ZnFe₂O₄ was subsequently obtained when a heat treatment was conducted at 500°C for 2 h. On the other hand, in order to examine the effect of particle size on magnetic characteristics of Ni-Zn ferrites, nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders with particle sizes of approximately 7, 25 and 100 nm were prepared by coprecipitation and citrate precursor methods. The magnetic characteristics of the ultrafine (7 nm) and coarse (100 nm) nanocrystalline ferrites showed differences. These differences are attributed to cation disordering at the surfaces of particles, wich becomes increasingly dominant as the particle size decreases.
format Article
author Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
spellingShingle Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
Functional Materials
author_facet Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
author_sort Jong-Chul Lee
title Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_short Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_full Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_fullStr Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_full_unstemmed Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_sort chemical synthesis of nanocrystalline ni-zn ferrites and their magnetic characteristics
publisher НТК «Інститут монокристалів» НАН України
publishDate 2006
url http://dspace.nbuv.gov.ua/handle/123456789/134187
citation_txt Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ.
series Functional Materials
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