Application of the Judd-Ofelt theory to Pr³⁺ ions in Y₂SiO₅ crystals
The results of the Judd-Ofelt theory application to Pr³⁺ doped Y₂SiO₅ are presented. For the first time for this matrix, the Ω₂, Ω₄, Ω₆ parameters have been determined and radiative lifetimes of ³P₀ and ¹D₂ multiplet states have been calculated basing on those parameters. The lifetimes obtained allo...
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| Date: | 2007 |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
НТК «Інститут монокристалів» НАН України
2007
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| Series: | Functional Materials |
| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/135612 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Application of the Judd-Ofelt theory to Pr³⁺ ions in Y₂SiO₅ crystals / P.N. Zhmurin // Functional Materials. — 2007. — Т. 14, № 1. — С. 15-18. — Бібліогр.: 13 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | The results of the Judd-Ofelt theory application to Pr³⁺ doped Y₂SiO₅ are presented. For the first time for this matrix, the Ω₂, Ω₄, Ω₆ parameters have been determined and radiative lifetimes of ³P₀ and ¹D₂ multiplet states have been calculated basing on those parameters. The lifetimes obtained allow the significant influence of the channels of nonradiative quenching for the ³P₀ state to be revealed. A more precise coincidence of calculated and observed spectroscopic characteristics can be obtained only when taking into account the influence of 4f5d electron states on 4f² electron shell properties that is not considered in the framework of the Judd-Ofelt theory. |
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