Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions

Effect of isomorphic anionic substitutions in the apatite-like calcium structures on their electron structure has been investigated. Changes in the electron subsystem of the first synthesized compounds Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) (where М = F⁻,СI⁻, х - 0, 1, 3, 5, 6) caused by isomorphic anionic subs...

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Дата:	2005
Автори:	Shpak, A.P., Karbovskii, V.L., Kurgan, N.A., Getman, E.I., Senkevich, A.I., Marchenko, V.I.
Формат:	Стаття
Мова:	English
Опубліковано:	НТК «Інститут монокристалів» НАН України 2005
Назва видання:	Functional Materials
Онлайн доступ:	http://dspace.nbuv.gov.ua/handle/123456789/138885
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Назва журналу:	Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions / A.P. Shpak, V.L. Karbovskii, N.A. Kurgan, E.I. Getman, A.I. Senkevich, V.I. Marchenko // Functional Materials. — 2005. — Т. 12, № 4. — С. 695-699. — Бібліогр.: 8 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine

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spelling	irk-123456789-1388852018-06-20T03:11:32Z Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions Shpak, A.P. Karbovskii, V.L. Kurgan, N.A. Getman, E.I. Senkevich, A.I. Marchenko, V.I. Effect of isomorphic anionic substitutions in the apatite-like calcium structures on their electron structure has been investigated. Changes in the electron subsystem of the first synthesized compounds Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) (where М = F⁻,СI⁻, х - 0, 1, 3, 5, 6) caused by isomorphic anionic substitutions have been investigated using spectral and structural methods. It is established that fluorine and chlorine containing compounds are characterized by a general behavior tendency of the local electronic densities on calcium and oxygen atoms at the variation of anionic group number that evidences the electron structure independence of the anion type on the c-axis. Дослiджено вплив анiонних iзоморфних замiщень у апатитоподiбних структурах кальцiю на їх електронну будову. Спектральними та структурними методами дослiджено змiни у електроннiй пiдсистемi вперше синтезованих сполук Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) (де М = F⁻,СI⁻, х - 0, 1, 3, 5, 6) при iзоморфних анiонних замiщеннях. Встановлено, що сполуки з фтором та хлором характеризуються загальною тенденцiєЮ поведiнки локальної електронної густини на атомах кальцiю та кисню при варiюваннi кiлькостi анiонних груп, що свiдчить про незалежнiсть електронної структури вiд типу анiона на осi c. Исследовано влияние анионных изоморфных замещений в апатитоподобных структурах кальция на их электронное строение. Спектральными и структурными методами исследованы изменения в электронной подсистеме при изоморфных анионных замещениях впервые синтезированных соединений Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) , где М = F⁻,СI⁻, х - 0, 1, 3, 5, 6). Установлено, что соединения с фтором и хлором характеризуются общей тенденцией поведения локальной электронной плотности на атомах кальция и кислорода при варьировании количества анионных групп, что свидетельствует о независимости электронной структуры от типа аниона на оси c. 2005 Article Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions / A.P. Shpak, V.L. Karbovskii, N.A. Kurgan, E.I. Getman, A.I. Senkevich, V.I. Marchenko // Functional Materials. — 2005. — Т. 12, № 4. — С. 695-699. — Бібліогр.: 8 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/138885 en Functional Materials НТК «Інститут монокристалів» НАН України
institution	Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection	DSpace DC
language	English
description	Effect of isomorphic anionic substitutions in the apatite-like calcium structures on their electron structure has been investigated. Changes in the electron subsystem of the first synthesized compounds Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) (where М = F⁻,СI⁻, х - 0, 1, 3, 5, 6) caused by isomorphic anionic substitutions have been investigated using spectral and structural methods. It is established that fluorine and chlorine containing compounds are characterized by a general behavior tendency of the local electronic densities on calcium and oxygen atoms at the variation of anionic group number that evidences the electron structure independence of the anion type on the c-axis.
format	Article
author	Shpak, A.P. Karbovskii, V.L. Kurgan, N.A. Getman, E.I. Senkevich, A.I. Marchenko, V.I.
spellingShingle	Shpak, A.P. Karbovskii, V.L. Kurgan, N.A. Getman, E.I. Senkevich, A.I. Marchenko, V.I. Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions Functional Materials
author_facet	Shpak, A.P. Karbovskii, V.L. Kurgan, N.A. Getman, E.I. Senkevich, A.I. Marchenko, V.I.
author_sort	Shpak, A.P.
title	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
title_short	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
title_full	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
title_fullStr	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
title_full_unstemmed	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
title_sort	electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions
publisher	НТК «Інститут монокристалів» НАН України
publishDate	2005
url	http://dspace.nbuv.gov.ua/handle/123456789/138885
citation_txt	Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions / A.P. Shpak, V.L. Karbovskii, N.A. Kurgan, E.I. Getman, A.I. Senkevich, V.I. Marchenko // Functional Materials. — 2005. — Т. 12, № 4. — С. 695-699. — Бібліогр.: 8 назв. — англ.
series	Functional Materials
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first_indexed	2025-07-10T06:46:39Z
last_indexed	2025-07-10T06:46:39Z
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Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions

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