Temperature dependences of the Peclet number in sublimation processes of simple substances

The results of calculating the Peclet number Ре = wr/(ρD) (where D is the diffusion coefficient; w is the evaporation rate of the substance; ρ is the density of the substance; r is the size factor) in sublimation processes of simple substances with high values of vapor pressure (≈ 1 mm Hg and above...

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Бібліографічні деталі
Дата:2022
Автори: Kravchenko, A.I., Zhukov, A.I., Datsenko, O.A.
Формат: Стаття
Мова:English
Опубліковано: Національний науковий центр «Харківський фізико-технічний інститут» НАН України 2022
Назва видання:Вопросы атомной науки и техники
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/195825
Теги: Додати тег
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Temperature dependences of the Peclet number in sublimation processes of simple substances / A.I. Kravchenko, A.I. Zhukov, O.A. Datsenko // Problems of Atomic Science and Technology. — 2022. — № 1. — С. 13-16. — Бібліогр.: 14 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The results of calculating the Peclet number Ре = wr/(ρD) (where D is the diffusion coefficient; w is the evaporation rate of the substance; ρ is the density of the substance; r is the size factor) in sublimation processes of simple substances with high values of vapor pressure (≈ 1 mm Hg and above at the melting temperature): As, Gd, Tm, Lu, Cr, Yb, Sm, Mg, Ra, Ca, Sr, Ni, Co, Eu, Mn, Ba. It is shown that the nature of the temperature dependence Pe(T) is determined by the properties of the components of the sublimated system “base–impurity” (including the diffusion activation energy Q of impurity). For each substance for given Q and r, the dependence Pe(T) is monotonic. A decrease in the process temperature can improve the purification of a substance from one of several impurities, accompanied by deterioration in the purification from another impurity.