Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
The solution of the associative mean-spherical approximation for ion- dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterparts in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expr...
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Date: | 2007 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Published: |
Інститут фізики конденсованих систем НАН України
2007
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Series: | Condensed Matter Physics |
Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/118702 |
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Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Cite this: | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation / M.F. Holovko, V.I. Kapko // Condensed Matter Physics. — 2007. — Т. 10, № 3(51). — С. 397-406. — Бібліогр.: 33 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of UkraineSummary: | The solution of the associative mean-spherical approximation for ion- dipolar system is reinvestigated and
expressed in terms of only five parameters. Three of them have counterparts in the case without association,
and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic
quantities are represented in a simpler form. Numerical results for thermodynamic properties and
phase equilibria are presented. |
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