Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation

The solution of the associative mean-spherical approximation for ion- dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterparts in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expr...

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Bibliographic Details
Date:2007
Main Authors: Holovko, M.F., Kapko, V.I.
Format: Article
Language:English
Published: Інститут фізики конденсованих систем НАН України 2007
Series:Condensed Matter Physics
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/118702
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation / M.F. Holovko, V.I. Kapko // Condensed Matter Physics. — 2007. — Т. 10, № 3(51). — С. 397-406. — Бібліогр.: 33 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The solution of the associative mean-spherical approximation for ion- dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterparts in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic quantities are represented in a simpler form. Numerical results for thermodynamic properties and phase equilibria are presented.