Peroxyhydrocarbonate and peroxocarbonate ions as typical α-nucleophiles in phosphonyl transfer
In a search for novel, high-reactivity, α-nucleophiles we examined the kinetics of decomposition of 4-nitrophenyldiethyl phosphonate (NPDEPN) by Н₂О₂/NH₄HCO₃/HО⁻ at рН 7.7—10.4. This system generates HCO₄⁻ and CO₄²⁻, and their equilibrium concentrations were calculated with the corresponding equilib...
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| Date: | 2011 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Published: |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України
2011
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| Series: | Украинский химический журнал |
| Subjects: | |
| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/186229 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Peroxyhydrocarbonate and peroxocarbonate ions as typical α-nucleophiles in phosphonyl transfer / T.M. Prokop’eva, Yu.S. Sadovskii, V.A. Savyolova, T.N. Solomoichenko, Zh.P. Piskunova, C.A. Bunton, A.F. Popov // Украинский химический журнал. — 2011. — Т. 77, № 1. — С. 54-60. — Бібліогр.: 31 назв. — англ. |